Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts

Fast, efficient, and highly stereoselective epoxidation with H 2O2 is reached by manganese coordination complexes with e-rich aminopyridine tetradentate ligands. It is shown that the electronic properties of these catalysts vary systematically with the stereoselectivity of the O-atom transfer event...

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Detalles Bibliográficos
Autores: Cussó Forest, Olaf, Garcia Bosch, Isaac, Font Gimbernat, David, Ribas Salamaña, Xavi, Lloret Fillol, Julio, Costas Salgueiro, Miquel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/10177
Acceso en línea:http://hdl.handle.net/10256/10177
Access Level:acceso embargado
Palabra clave:Epòxids
Epoxy compounds
Compostos heterocíclics
Heterocyclic compounds
Catalitzadors
Catalysts
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spelling Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalystsCussó Forest, OlafGarcia Bosch, IsaacFont Gimbernat, DavidRibas Salamaña, XaviLloret Fillol, JulioCostas Salgueiro, MiquelEpòxidsEpoxy compoundsCompostos heterocíclicsHeterocyclic compoundsCatalitzadorsCatalystsFast, efficient, and highly stereoselective epoxidation with H 2O2 is reached by manganese coordination complexes with e-rich aminopyridine tetradentate ligands. It is shown that the electronic properties of these catalysts vary systematically with the stereoselectivity of the O-atom transfer event and exert fine control over the activation of hydrogen peroxide, reducing the amount of carboxylic acid co-catalyst necessary for efficient operationAmerican Chemical Society (ACS)European Research CouncilMinisterio de Economía y Competitividad (Espanya)Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de RecercaMinisterio de Ciencia e Innovación (Espanya)infoinfo2013info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10256/10177http://hdl.handle.net/10256/10177© Organic Letters, 2013, vol. 15, p. 6158-6161Articles publicats (D-Q)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1021/ol403018xinfo:eu-repo/semantics/altIdentifier/issn/1523-7060info:eu-repo/semantics/altIdentifier/eissn/1523-7052info:eu-repo/grantAgreement/MINECO//CTQ2012-37420-C02-01MICINN/PN 2010-2016/CSD2010-00065AGAUR/2009-2014/2009 SGR-637info:eu-repo/grantAgreement/EC/FP7/239910Tots els drets reservatsinfo:eu-repo/semantics/embargoedAccessoai:recercat.cat:10256/101772026-05-29T05:05:01Z
dc.title.none.fl_str_mv Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
title Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
spellingShingle Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
Cussó Forest, Olaf
Epòxids
Epoxy compounds
Compostos heterocíclics
Heterocyclic compounds
Catalitzadors
Catalysts
title_short Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
title_full Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
title_fullStr Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
title_full_unstemmed Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
title_sort Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
dc.creator.none.fl_str_mv Cussó Forest, Olaf
Garcia Bosch, Isaac
Font Gimbernat, David
Ribas Salamaña, Xavi
Lloret Fillol, Julio
Costas Salgueiro, Miquel
author Cussó Forest, Olaf
author_facet Cussó Forest, Olaf
Garcia Bosch, Isaac
Font Gimbernat, David
Ribas Salamaña, Xavi
Lloret Fillol, Julio
Costas Salgueiro, Miquel
author_role author
author2 Garcia Bosch, Isaac
Font Gimbernat, David
Ribas Salamaña, Xavi
Lloret Fillol, Julio
Costas Salgueiro, Miquel
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv European Research Council
Ministerio de Economía y Competitividad (Espanya)
Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca
Ministerio de Ciencia e Innovación (Espanya)
dc.subject.none.fl_str_mv Epòxids
Epoxy compounds
Compostos heterocíclics
Heterocyclic compounds
Catalitzadors
Catalysts
topic Epòxids
Epoxy compounds
Compostos heterocíclics
Heterocyclic compounds
Catalitzadors
Catalysts
description Fast, efficient, and highly stereoselective epoxidation with H 2O2 is reached by manganese coordination complexes with e-rich aminopyridine tetradentate ligands. It is shown that the electronic properties of these catalysts vary systematically with the stereoselectivity of the O-atom transfer event and exert fine control over the activation of hydrogen peroxide, reducing the amount of carboxylic acid co-catalyst necessary for efficient operation
publishDate 2013
dc.date.none.fl_str_mv 2013
info
info
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/10177
http://hdl.handle.net/10256/10177
url http://hdl.handle.net/10256/10177
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ol403018x
info:eu-repo/semantics/altIdentifier/issn/1523-7060
info:eu-repo/semantics/altIdentifier/eissn/1523-7052
info:eu-repo/grantAgreement/MINECO//CTQ2012-37420-C02-01
MICINN/PN 2010-2016/CSD2010-00065
AGAUR/2009-2014/2009 SGR-637
info:eu-repo/grantAgreement/EC/FP7/239910
dc.rights.none.fl_str_mv Tots els drets reservats
info:eu-repo/semantics/embargoedAccess
rights_invalid_str_mv Tots els drets reservats
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society (ACS)
publisher.none.fl_str_mv American Chemical Society (ACS)
dc.source.none.fl_str_mv © Organic Letters, 2013, vol. 15, p. 6158-6161
Articles publicats (D-Q)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.81155

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