A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries

Hollow MnFeO nanoparticles (NPs) with an average size of 15 nm are produced from the solid state reaction of FeO-MnO heterostructures. These heterostructures are synthesized through the seeded-growth of MnO crystal domains on the surface of hollow FeO NPs obtained by the nanoscale Kirkendall effect....

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Autores: Yu, Xiaoting|||0000-0003-0457-4047, Zhang, Chaoqi|||0000-0002-0357-235X, Luo, Zhishan|||0000-0002-0801-9238, Zhang, Ting|||0000-0002-0317-9662, Liu, Junfeng|||0000-0003-3164-6472, Li, Junshan|||0000-0002-1482-1972, Zuo, Yong|||0000-0003-1564-467X, Jacas Biendicho, Jordi|||0000-0001-5981-6168, Llorca, Jordi|||0000-0002-7447-9582, Arbiol i Cobos, Jordi|||0000-0002-0695-1726, Morante, Joan Ramon|||0000-0002-4981-4633, Cabot i Codina, Andreu|||0000-0002-7533-3251
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:220664
Acceso en línea:https://ddd.uab.cat/record/220664
https://dx.doi.org/urn:doi:10.1016/j.nanoen.2019.104199
Access Level:acceso abierto
Palabra clave:Ferrite
Lithium-ion battery
Kirkendall effect
Hollow nanoparticle
Iron oxide
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spelling A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteriesYu, Xiaoting|||0000-0003-0457-4047Zhang, Chaoqi|||0000-0002-0357-235XLuo, Zhishan|||0000-0002-0801-9238Zhang, Ting|||0000-0002-0317-9662Liu, Junfeng|||0000-0003-3164-6472Li, Junshan|||0000-0002-1482-1972Zuo, Yong|||0000-0003-1564-467XJacas Biendicho, Jordi|||0000-0001-5981-6168Llorca, Jordi|||0000-0002-7447-9582Arbiol i Cobos, Jordi|||0000-0002-0695-1726Morante, Joan Ramon|||0000-0002-4981-4633Cabot i Codina, Andreu|||0000-0002-7533-3251FerriteLithium-ion batteryKirkendall effectHollow nanoparticleIron oxideHollow MnFeO nanoparticles (NPs) with an average size of 15 nm are produced from the solid state reaction of FeO-MnO heterostructures. These heterostructures are synthesized through the seeded-growth of MnO crystal domains on the surface of hollow FeO NPs obtained by the nanoscale Kirkendall effect. FeO-MnO heterostructures are subsequently annealed at 500 °C, enough temperature to promote the interfusion of Fe and Mn ions, but without compromising the hollow geometry. MnFeO nanostructures are tested as anode in lithium-ion batteries (LIBs), delivering large lithium storage capacities and high-rate capabilities of 1054 mAh g at 0.1 A g and 369 mAh g at 5 A g. Additionally, hollow MnFeO NPs display long cycling stability, with a capacity up to 887 mAh g at 0.3 A g after 450 cycles. The excellent performance of hollow MnFeO NPs as anode for LIBs is associated with their crystal structure, composition, and the presence of carbonized ligands, which further promote electrical conductivity and buffer the volume changes during cycling. Additionally, the small particle size and hollow morphology improves the lithium kinetics, structural stability and cycling performance. 22019-01-0120192019-01-01Articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/220664https://dx.doi.org/urn:doi:10.1016/j.nanoen.2019.104199reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 ENE2016-77798-C4-3-RAgència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-327Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2017-0706Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 ENE2017-85087-C3Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-128Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 ENE2015-63969-Ropen accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, i la comunicació pública de l'obra, sempre que no sigui amb finalitats comercials, i sempre que es reconegui l'autoria de l'obra original. No es permet la creació d'obres derivades.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2206642026-06-06T12:50:31Z
dc.title.none.fl_str_mv A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries
title A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries
spellingShingle A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries
Yu, Xiaoting|||0000-0003-0457-4047
Ferrite
Lithium-ion battery
Kirkendall effect
Hollow nanoparticle
Iron oxide
title_short A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries
title_full A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries
title_fullStr A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries
title_full_unstemmed A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries
title_sort A low temperature solid state reaction to produce hollow MnxFe3-xO4 nanoparticles as anode for lithium-ion batteries
dc.creator.none.fl_str_mv Yu, Xiaoting|||0000-0003-0457-4047
Zhang, Chaoqi|||0000-0002-0357-235X
Luo, Zhishan|||0000-0002-0801-9238
Zhang, Ting|||0000-0002-0317-9662
Liu, Junfeng|||0000-0003-3164-6472
Li, Junshan|||0000-0002-1482-1972
Zuo, Yong|||0000-0003-1564-467X
Jacas Biendicho, Jordi|||0000-0001-5981-6168
Llorca, Jordi|||0000-0002-7447-9582
Arbiol i Cobos, Jordi|||0000-0002-0695-1726
Morante, Joan Ramon|||0000-0002-4981-4633
Cabot i Codina, Andreu|||0000-0002-7533-3251
author Yu, Xiaoting|||0000-0003-0457-4047
author_facet Yu, Xiaoting|||0000-0003-0457-4047
Zhang, Chaoqi|||0000-0002-0357-235X
Luo, Zhishan|||0000-0002-0801-9238
Zhang, Ting|||0000-0002-0317-9662
Liu, Junfeng|||0000-0003-3164-6472
Li, Junshan|||0000-0002-1482-1972
Zuo, Yong|||0000-0003-1564-467X
Jacas Biendicho, Jordi|||0000-0001-5981-6168
Llorca, Jordi|||0000-0002-7447-9582
Arbiol i Cobos, Jordi|||0000-0002-0695-1726
Morante, Joan Ramon|||0000-0002-4981-4633
Cabot i Codina, Andreu|||0000-0002-7533-3251
author_role author
author2 Zhang, Chaoqi|||0000-0002-0357-235X
Luo, Zhishan|||0000-0002-0801-9238
Zhang, Ting|||0000-0002-0317-9662
Liu, Junfeng|||0000-0003-3164-6472
Li, Junshan|||0000-0002-1482-1972
Zuo, Yong|||0000-0003-1564-467X
Jacas Biendicho, Jordi|||0000-0001-5981-6168
Llorca, Jordi|||0000-0002-7447-9582
Arbiol i Cobos, Jordi|||0000-0002-0695-1726
Morante, Joan Ramon|||0000-0002-4981-4633
Cabot i Codina, Andreu|||0000-0002-7533-3251
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Ferrite
Lithium-ion battery
Kirkendall effect
Hollow nanoparticle
Iron oxide
topic Ferrite
Lithium-ion battery
Kirkendall effect
Hollow nanoparticle
Iron oxide
description Hollow MnFeO nanoparticles (NPs) with an average size of 15 nm are produced from the solid state reaction of FeO-MnO heterostructures. These heterostructures are synthesized through the seeded-growth of MnO crystal domains on the surface of hollow FeO NPs obtained by the nanoscale Kirkendall effect. FeO-MnO heterostructures are subsequently annealed at 500 °C, enough temperature to promote the interfusion of Fe and Mn ions, but without compromising the hollow geometry. MnFeO nanostructures are tested as anode in lithium-ion batteries (LIBs), delivering large lithium storage capacities and high-rate capabilities of 1054 mAh g at 0.1 A g and 369 mAh g at 5 A g. Additionally, hollow MnFeO NPs display long cycling stability, with a capacity up to 887 mAh g at 0.3 A g after 450 cycles. The excellent performance of hollow MnFeO NPs as anode for LIBs is associated with their crystal structure, composition, and the presence of carbonized ligands, which further promote electrical conductivity and buffer the volume changes during cycling. Additionally, the small particle size and hollow morphology improves the lithium kinetics, structural stability and cycling performance.
publishDate 2019
dc.date.none.fl_str_mv 2
2019-01-01
2019
2019-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/220664
https://dx.doi.org/urn:doi:10.1016/j.nanoen.2019.104199
url https://ddd.uab.cat/record/220664
https://dx.doi.org/urn:doi:10.1016/j.nanoen.2019.104199
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 ENE2016-77798-C4-3-R
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-327
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2017-0706
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 ENE2017-85087-C3
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-128
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 ENE2015-63969-R
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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