Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN

11 pags., 2 figs., 2 tabs.

Detalles Bibliográficos
Autores: Cabezas, Carlos, Endo, Yasuki, Cernicharo, José
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2021
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/248951
Acceso en línea:http://hdl.handle.net/10261/248951
Access Level:acceso abierto
Palabra clave:Cyanomethyl radical
Deuterated species
Rotational spectrum
FTMW spectroscopy
TMC–1
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spelling Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCNCabezas, CarlosEndo, YasukiCernicharo, JoséCyanomethyl radicalDeuterated speciesRotational spectrumFTMW spectroscopyTMC–111 pags., 2 figs., 2 tabs.The microwave spectrum of the doubly deuterated cyanomethyl radical (DCCN) in its ground electronic state (B) has been observed for the lowest four rotational transitions (N = 1–0, 2–1, 2–1 and 2–1) using a Fourier transform microwave spectrometer in combination with a pulsed discharge nozzle. A total of 394 hyperfine components were measured and subjected to a least squares analysis which allowed determining twelve hyperfine constants for nitrogen and deuterium nuclei. With this new set of molecular constants we obtained accurate predictions for low N rotational transitions with hyperfine structure, and searched for this species in TMC–1.C. C. and J. C. thank to the European Research Council for fund-ing support under Synergy Grant ERC-2013-SyG, G.A. 610256 (NANOCOSMOS) and to Ministerio de Ciencia e Innovación for funding support through projects AYA2016–75066–C2–1–P andPID2019–107115GB–C21. Y. E. thanks Ministry of Science and Technology of Taiwan for funding support under grant MOST108–2113–M–009–25.Academic PressEuropean CommissionMinisterio de Economía y Competitividad (España)Ministerio de Ciencia, Innovación y Universidades (España)Ministry of Science and Technology (Taiwan)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2021202120212021info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/248951reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/FP7/610256info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AYA2016–75066–C2–1–Pinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019–107115GB–C21http://dx.doi.org/10.1016/j.jms.2021.111448Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2489512026-05-22T06:33:51Z
dc.title.none.fl_str_mv Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN
title Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN
spellingShingle Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN
Cabezas, Carlos
Cyanomethyl radical
Deuterated species
Rotational spectrum
FTMW spectroscopy
TMC–1
title_short Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN
title_full Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN
title_fullStr Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN
title_full_unstemmed Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN
title_sort Laboratory microwave spectroscopy of the doubly deuterated cyanomethyl radical, D2CCN
dc.creator.none.fl_str_mv Cabezas, Carlos
Endo, Yasuki
Cernicharo, José
author Cabezas, Carlos
author_facet Cabezas, Carlos
Endo, Yasuki
Cernicharo, José
author_role author
author2 Endo, Yasuki
Cernicharo, José
author2_role author
author
dc.contributor.none.fl_str_mv European Commission
Ministerio de Economía y Competitividad (España)
Ministerio de Ciencia, Innovación y Universidades (España)
Ministry of Science and Technology (Taiwan)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Cyanomethyl radical
Deuterated species
Rotational spectrum
FTMW spectroscopy
TMC–1
topic Cyanomethyl radical
Deuterated species
Rotational spectrum
FTMW spectroscopy
TMC–1
description 11 pags., 2 figs., 2 tabs.
publishDate 2021
dc.date.none.fl_str_mv 2021
2021
2021
2021
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/248951
url http://hdl.handle.net/10261/248951
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/FP7/610256
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AYA2016–75066–C2–1–P
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019–107115GB–C21
http://dx.doi.org/10.1016/j.jms.2021.111448
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Academic Press
publisher.none.fl_str_mv Academic Press
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.812429

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