Highly Efficient Organocatalyzed Conversion of Oxiranes and CO2 into Organic Carbonates
<p> <span style="color: rgb(51, 51, 51); font-family: 'Open Sans', Arial, Helvetica, 'Lucida Sans Unicode', sans-serif; font-size: 16px; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: normal; line-height: 24px; orphans: auto; text-ali...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305826 |
| Acceso en línea: | http://hdl.handle.net/2072/305826 https://doi.org/10.1002/cssc.201500710 |
| Access Level: | acceso abierto |
| Palabra clave: | carbon dioxide hydrogen bonding organic carbonates synergy tannic acid organocatalysis |
| Sumario: | <p> <span style="color: rgb(51, 51, 51); font-family: 'Open Sans', Arial, Helvetica, 'Lucida Sans Unicode', sans-serif; font-size: 16px; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: normal; line-height: 24px; orphans: auto; text-align: start; text-indent: 0px; text-transform: none; white-space: normal; widows: 1; word-spacing: 0px; -webkit-text-stroke-width: 0px; display: inline !important; float: none; background-color: rgb(249, 249, 249);">A binary catalyst system based on tannic acid/NBu</span><sub style="line-height: 0; bottom: -0.25em; margin: 0px; padding: 0px 1px; border: 0px; outline: 0px; font-size: 0.688em; vertical-align: baseline; position: relative; color: rgb(51, 51, 51); font-family: 'Open Sans', Arial, Helvetica, 'Lucida Sans Unicode', sans-serif; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: normal; orphans: auto; text-align: start; text-indent: 0px; text-transform: none; white-space: normal; widows: 1; word-spacing: 0px; -webkit-text-stroke-width: 0px; background: 0px 0px rgb(249, 249, 249);">4</sub><span style="color: rgb(51, 51, 51); font-family: 'Open Sans', Arial, Helvetica, 'Lucida Sans Unicode', sans-serif; font-size: 16px; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: normal; line-height: 24px; orphans: auto; text-align: start; text-indent: 0px; text-transform: none; white-space: normal; widows: 1; word-spacing: 0px; -webkit-text-stroke-width: 0px; display: inline !important; float: none; background-color: rgb(249, 249, 249);">X (X=Br, I) is presented as a highly efficient organocatalyst at very low catalyst loading for the coupling of carbon dioxide and functional oxiranes to afford organic carbonates in good yields. The presence of multiple polyphenol fragments within the tannic acid structure is considered to be beneficial for synergistic effects that lead to higher stabilization of the catalyst structure during catalysis. The observed turnover frequencies (TOFs) exceed 200 h</span><sup style="line-height: 0; top: -0.5em; margin: 0px; padding: 0px 1px; border: 0px; outline: 0px; font-size: 0.688em; vertical-align: baseline; position: relative; color: rgb(51, 51, 51); font-family: 'Open Sans', Arial, Helvetica, 'Lucida Sans Unicode', sans-serif; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: normal; orphans: auto; text-align: start; text-indent: 0px; text-transform: none; white-space: normal; widows: 1; word-spacing: 0px; -webkit-text-stroke-width: 0px; background: 0px 0px rgb(249, 249, 249);">−1</sup><span style="color: rgb(51, 51, 51); font-family: 'Open Sans', Arial, Helvetica, 'Lucida Sans Unicode', sans-serif; font-size: 16px; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: normal; line-height: 24px; orphans: auto; text-align: start; text-indent: 0px; text-transform: none; white-space: normal; widows: 1; word-spacing: 0px; -webkit-text-stroke-width: 0px; display: inline !important; float: none; background-color: rgb(249, 249, 249);"><span class="Apple-converted-space"> </span>and are among the highest reported to date for organocatalysts in this area of CO</span><sub style="line-height: 0; bottom: -0.25em; margin: 0px; padding: 0px 1px; border: 0px; outline: 0px; font-size: 0.688em; vertical-align: baseline; position: relative; color: rgb(51, 51, 51); font-family: 'Open Sans', Arial, Helvetica, 'Lucida Sans Unicode', sans-serif; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: normal; orphans: auto; text-align: start; text-indent: 0px; text-transform: none; white-space: normal; widows: 1; word-spacing: 0px; -webkit-text-stroke-width: 0px; background: 0px 0px rgb(249, 249, 249);">2</sub><span style="color: rgb(51, 51, 51); font-family: 'Open Sans', Arial, Helvetica, 'Lucida Sans Unicode', sans-serif; font-size: 16px; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: |
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