Self-assembly and lateral cobalt coordination of a five-fold symmetric cyanostar macrocycle on a Au(111) surface
The functionalization of solid surfaces with responsive macrocyclic compounds is a key strategy for developing advanced functional materials, with applications in molecular sensing, catalysis, and nanoscale electronics. Here,we report the self-assembly and lateral cobalt coordination, on an Au(111)...
| Autores: | , , , , , , , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2025 |
| País: | España |
| Institución: | Universidad Autónoma de Madrid |
| Repositorio: | Biblos-e Archivo. Repositorio Institucional de la UAM |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.uam.es:10486/749000 |
| Acceso en línea: | https://hdl.handle.net/10486/749000 https://dx.doi.org/10.1002/chem.202503051 |
| Access Level: | acceso abierto |
| Palabra clave: | cyanostar metal-ligand coordination on-surface chemistry scanning tunneling microscopy self-assembly Química |
| Sumario: | The functionalization of solid surfaces with responsive macrocyclic compounds is a key strategy for developing advanced functional materials, with applications in molecular sensing, catalysis, and nanoscale electronics. Here,we report the self-assembly and lateral cobalt coordination, on an Au(111) surface and under ultra-high vacuum conditions, of a fivefold symmetric cyanostar macrocycle, a class of anion recognition molecules. This represents the first example of a close-packed regular assembly of a pentagonal macrocycle at the solid-vacuum interface |
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