Enhanced CO2 affinity in a metal-organic framework through green incorporation of a dual-functional amino acid
Post-synthetic incorporation of amino acids into the Zr-based metal-organic framework DUT-67 via relatively green methods yields materials with enhanced CO2 affinity. Structural and sorption studies reveal high affinity for DUT-67-Trp, exploiting its dual functionality to achieve an adsorption entha...
| Autores: | , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2025 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/422065 |
| Acceso en línea: | http://hdl.handle.net/10261/422065 https://api.elsevier.com/content/abstract/scopus_id/105027525329 |
| Access Level: | acceso abierto |
| Sumario: | Post-synthetic incorporation of amino acids into the Zr-based metal-organic framework DUT-67 via relatively green methods yields materials with enhanced CO2 affinity. Structural and sorption studies reveal high affinity for DUT-67-Trp, exploiting its dual functionality to achieve an adsorption enthalpy level comparable to those of high-performing frameworks. The findings provide a promising pathway towards developing sustainable amino-functionalized CO2 sorbents. |
|---|