Enhanced CO₂ affinity in a metal-organic framework through green incorporation of a dual-functional amino acid
Post-synthetic incorporation of amino acids into the Zr-based metalorganic framework DUT-67 via relatively green methods yields materials with enhanced CO2 affinity. Structural and sorption studies reveal high affinity for DUT-67-Trp, exploiting its dual functionality to achieve an adsorption enthal...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2025 |
| País: | España |
| Institución: | Universidad Autónoma de Madrid |
| Repositorio: | Biblos-e Archivo. Repositorio Institucional de la UAM |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.uam.es:10486/740760 |
| Acceso en línea: | https://hdl.handle.net/10486/740760 https://dx.doi.org/10.1039/D5NR03069B |
| Access Level: | acceso abierto |
| Palabra clave: | Carbon dioxide Crystalline materials amino acid Química |
| Sumario: | Post-synthetic incorporation of amino acids into the Zr-based metalorganic framework DUT-67 via relatively green methods yields materials with enhanced CO2 affinity. Structural and sorption studies reveal high affinity for DUT-67-Trp, exploiting its dual functionality to achieve an adsorption enthalpy level comparable to those of highperforming frameworks. The findings provide a promising pathway towards developing sustainable amino-functionalized CO2 sorbents |
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