Optimizing the thermoelectric efficiency of icosahedral quasicrystals and related complex alloys

In this work we analyze the potential role of quasicrystals and related alloys in thermoelectric material research. Relatively large figure of merit values are expected for those samples exhibiting two properly located narrow features in the density of states close to the Fermi level. It is expected...

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Detalles Bibliográficos
Autor: Maciá Barber, Enrique Alfonso
Tipo de recurso: artículo
Fecha de publicación:2009
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/42726
Acceso en línea:https://hdl.handle.net/20.500.14352/42726
Access Level:acceso abierto
Palabra clave:538.9
Density-of-states
Al-Cu-Fe
Composition dependence
Thermal-conductivity
Electronic transport
Physical nature
Approximants
Phases
Clusters
Mn
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
Descripción
Sumario:In this work we analyze the potential role of quasicrystals and related alloys in thermoelectric material research. Relatively large figure of merit values are expected for those samples exhibiting two properly located narrow features in the density of states close to the Fermi level. It is expected that optimized quasicrystals will perform better at relatively low temperatures, whereas the ZT curve of complex metallic alloys reaches its maximum at high temperatures. Among state-of-the-art quasicrystals most promising samples for thermoelectric applications are found in the AlPd (Mn,Re) system. Quasicrystalline and related approximants in the ScMgCuGa and CaAuIn systems, synthesized on the basis of pseudogap tuning concepts, appear as promising candidates as well.