An efficient dynamic asymmetric catalytic system within a zinc-templated network
Enhanced cooperativity leading to high catalytic activity and stereoselectivity has been achieved through a complex network of simple species interacting reversibly. This novel dynamic catalytic system relies on bipyridine-based organocatalytic ligands and zinc(II) as the template. It demonstrates t...
| Autores: | , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/185362 |
| Acceso en línea: | http://hdl.handle.net/10261/185362 |
| Access Level: | acceso abierto |
| Palabra clave: | Catalysis Dynamic asymmetric catalytic system |
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An efficient dynamic asymmetric catalytic system within a zinc-templated networkSerra-Pont, AnnaAlfonso, IgnacioSolà Oller, JordiJimeno, CirilCatalysisDynamic asymmetric catalytic systemEnhanced cooperativity leading to high catalytic activity and stereoselectivity has been achieved through a complex network of simple species interacting reversibly. This novel dynamic catalytic system relies on bipyridine-based organocatalytic ligands and zinc(II) as the template. It demonstrates the effectiveness of dealing with mixtures rather than single species in asymmetric catalysis.We acknowledge support of the publication fee by the CSIC Open Access Support Initiative through its Unit of Information Resources for Research (URICI)Peer reviewedRoyal Society of Chemistry (UK)Consejo Superior de Investigaciones Científicas (España)Alfonso, Ignacio [0000-0003-0678-0362]Solà Oller, Jordi [0000-0002-3389-3429]Serra-Pont, Anna [0000-0002-7174-3712]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]201920192019info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/185362reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://doi.org/10.1039/C9CC03958ASíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1853622026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
An efficient dynamic asymmetric catalytic system within a zinc-templated network |
| title |
An efficient dynamic asymmetric catalytic system within a zinc-templated network |
| spellingShingle |
An efficient dynamic asymmetric catalytic system within a zinc-templated network Serra-Pont, Anna Catalysis Dynamic asymmetric catalytic system |
| title_short |
An efficient dynamic asymmetric catalytic system within a zinc-templated network |
| title_full |
An efficient dynamic asymmetric catalytic system within a zinc-templated network |
| title_fullStr |
An efficient dynamic asymmetric catalytic system within a zinc-templated network |
| title_full_unstemmed |
An efficient dynamic asymmetric catalytic system within a zinc-templated network |
| title_sort |
An efficient dynamic asymmetric catalytic system within a zinc-templated network |
| dc.creator.none.fl_str_mv |
Serra-Pont, Anna Alfonso, Ignacio Solà Oller, Jordi Jimeno, Ciril |
| author |
Serra-Pont, Anna |
| author_facet |
Serra-Pont, Anna Alfonso, Ignacio Solà Oller, Jordi Jimeno, Ciril |
| author_role |
author |
| author2 |
Alfonso, Ignacio Solà Oller, Jordi Jimeno, Ciril |
| author2_role |
author author author |
| dc.contributor.none.fl_str_mv |
Consejo Superior de Investigaciones Científicas (España) Alfonso, Ignacio [0000-0003-0678-0362] Solà Oller, Jordi [0000-0002-3389-3429] Serra-Pont, Anna [0000-0002-7174-3712] Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Catalysis Dynamic asymmetric catalytic system |
| topic |
Catalysis Dynamic asymmetric catalytic system |
| description |
Enhanced cooperativity leading to high catalytic activity and stereoselectivity has been achieved through a complex network of simple species interacting reversibly. This novel dynamic catalytic system relies on bipyridine-based organocatalytic ligands and zinc(II) as the template. It demonstrates the effectiveness of dealing with mixtures rather than single species in asymmetric catalysis. |
| publishDate |
2019 |
| dc.date.none.fl_str_mv |
2019 2019 2019 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/185362 |
| url |
http://hdl.handle.net/10261/185362 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
http://doi.org/10.1039/C9CC03958A Sí |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
Royal Society of Chemistry (UK) |
| publisher.none.fl_str_mv |
Royal Society of Chemistry (UK) |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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| repository.mail.fl_str_mv |
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1869407822936014848 |
| score |
15,812429 |