An efficient dynamic asymmetric catalytic system within a zinc-templated network

Enhanced cooperativity leading to high catalytic activity and stereoselectivity has been achieved through a complex network of simple species interacting reversibly. This novel dynamic catalytic system relies on bipyridine-based organocatalytic ligands and zinc(II) as the template. It demonstrates t...

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Detalles Bibliográficos
Autores: Serra-Pont, Anna, Alfonso, Ignacio, Solà Oller, Jordi, Jimeno, Ciril
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/185362
Acceso en línea:http://hdl.handle.net/10261/185362
Access Level:acceso abierto
Palabra clave:Catalysis
Dynamic asymmetric catalytic system
Descripción
Sumario:Enhanced cooperativity leading to high catalytic activity and stereoselectivity has been achieved through a complex network of simple species interacting reversibly. This novel dynamic catalytic system relies on bipyridine-based organocatalytic ligands and zinc(II) as the template. It demonstrates the effectiveness of dealing with mixtures rather than single species in asymmetric catalysis.