Development of advanced analytical methodologies based on gas chromatography coupled to mass spectometry for the determination of pops and vocs in the food and environmental field

The work in this thesis has been clearly divided into three parts: In the first part, efforts were directed to obtaining a trace level quantification method for halogenated flame retardants using high-volume injections and gas chromatography coupled to GC-MS/MS tandem mass spectrometry. In the secon...

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Detalles Bibliográficos
Autor: Sales Martínez, Carlos
Tipo de recurso: tesis doctoral
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:CBUC, CESCA
Repositorio:TDR. Tesis Doctorales en Red
OAI Identifier:oai:www.tdx.cat:10803/668939
Acceso en línea:http://hdl.handle.net/10803/668939
http://dx.doi.org/10.6035/14104.2019.177055
Access Level:acceso abierto
Palabra clave:Gas Chromatography
Volatiles
Pollutants
Mass Spectrometry
Purge and Trap
Metabolomics
Ciències naturals, químiques, físiques i matemàtiques
543
Descripción
Sumario:The work in this thesis has been clearly divided into three parts: In the first part, efforts were directed to obtaining a trace level quantification method for halogenated flame retardants using high-volume injections and gas chromatography coupled to GC-MS/MS tandem mass spectrometry. In the second part, the potential of the GC-MS / MS technique was evaluated together with the new atmospheric pressure chemical ionization source (APCI) for the quantification of PBDEs, NBFRs (including hexabromocyclododecane (HBCD)) and DL-PCBs at trace levels in food and environmental samples. In the third part, two untargeted analytical methodologies by GC-MS were developed as complementary tools to the PANEL TEST for the classification of olive oil samples according to their quality.