Transparent sol-gel oxyfluoride glass-ceramics with high crystalline fraction and study of re incorporation
Transparent oxyfluoride glass-ceramic films and self-supported layers with composition 80SiO2-20LaF3 doped with Er3+ have been successfully synthesized by sol-gel process for the first time. Crack-free films and self-supported layer with a maximum thickness up to 1.4 µm were obtained after heat trea...
| Autores: | , , , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Universidad Autónoma de Madrid |
| Repositorio: | Biblos-e Archivo. Repositorio Institucional de la UAM |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.uam.es:10486/715008 |
| Acceso en línea: | http://hdl.handle.net/10486/715008 https://dx.doi.org/10.3390/nano9040530 |
| Access Level: | acceso abierto |
| Palabra clave: | Glass-ceramic oxyfluoride rare-earth crystallization sol-gel Física |
| Sumario: | Transparent oxyfluoride glass-ceramic films and self-supported layers with composition 80SiO2-20LaF3 doped with Er3+ have been successfully synthesized by sol-gel process for the first time. Crack-free films and self-supported layer with a maximum thickness up to 1.4 µm were obtained after heat treatment at the low temperature of 550 ◦C for 1 min, resulting in a LaF3 crystal fraction of 18 wt%, as confirmed by quantitative Rietveld refinement. This is the highest value reported up to now for transparent oxyfluoride glass-ceramics prepared by sol-gel. This work provides a new synthesis strategy and opens the way to a wide range of potential applications of oxyfluoride glass-ceramics. The characterization by a wide range of techniques revealed the homogeneous precipitation of LaF3 nanocrystals into the glass matrix. X-ray absorption spectroscopy and electron paramagnetic resonance confirmed that the Er3+ ions are preferentially embedded in the low phonon-energy LaF3 nanocrystals. Moreover, photoluminescence (PL) measurements confirmed the incorporation of dopants in the LaF3 nanocrystals. The effective concentration of rare-earth ions in the LaF3 nanocrystals is also estimated by X-ray absorption spectroscopy |
|---|