Transparent Sol-Gel Oxyfluoride Glass-Ceramics with High Crystalline Fraction and Study of RE Incorporation
Transparent oxyfluoride glass-ceramic films and self-supported layers with composition 80SiO₂-20LaF₃ doped with Er3+ have been successfully synthesized by sol-gel process for the first time. Crack-free films and self-supported layer with a maximum thickness up to 1.4 m were obtained after heat treat...
| Autores: | , , , , , , , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Universidad del País Vasco |
| Repositorio: | Addi. Archivo Digital para la Docencia y la Investigación |
| OAI Identifier: | oai:addi.ehu.eus:10810/32683 |
| Acceso en línea: | http://hdl.handle.net/10810/32683 |
| Access Level: | acceso abierto |
| Palabra clave: | crystallization glass-ceramic oxyfluoride rare-earth sol-gel |
| Sumario: | Transparent oxyfluoride glass-ceramic films and self-supported layers with composition 80SiO₂-20LaF₃ doped with Er3+ have been successfully synthesized by sol-gel process for the first time. Crack-free films and self-supported layer with a maximum thickness up to 1.4 m were obtained after heat treatment at the low temperature of 550 °C for 1 min, resulting in a LaF₃ crystal fraction of 18 wt%, as confirmed by quantitative Rietveld refinement. This is the highest value reported up to now for transparent oxyfluoride glass-ceramics prepared by sol-gel. This work provides a new synthesis strategy and opens the way to a wide range of potential applications of oxyfluoride glass-ceramics. The characterization by a wide range of techniques revealed the homogeneous precipitation of LaF₃ nanocrystals into the glass matrix. X-ray absorption spectroscopy and electron paramagnetic resonance confirmed that the Er3+ ions are preferentially embedded in the low phonon-energy LaF₃ nanocrystals. Moreover, photoluminescence (PL) measurements confirmed the incorporation of dopants in the LaF₃ nanocrystals. The effective concentration of rare-earth ions in the LaF₃ nanocrystals is also estimated by X-ray absorption spectroscopy. |
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