3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths

Covalent organic frameworks (COFs) have witnessed outstanding developments in the past 15 years, particularly in optimizing their pore structures, linkages, and variety of monomers used in their synthesis. Yet, a significant challenge remains unaddressed: the processability of COFs into macroscopic...

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Detalles Bibliográficos
Autores: Royuela Collado, Sergio, Sevim, Semih, Hernanz, Guillermo, Rodríguez San Miguel, David, Franco, Carlos, Pané, Salvador, Puigmartí Luis, Josep, Zamora Abanades, Félix Juan, Fischer, Peter
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/710239
Acceso en línea:http://hdl.handle.net/10486/710239
https://dx.doi.org/10.1002/adfm.202314634
Access Level:acceso abierto
Palabra clave:3D printing
Covalent organic frameworks
Inks
Processing
Química
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spelling 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monolithsRoyuela Collado, SergioSevim, SemihHernanz, GuillermoRodríguez San Miguel, DavidFranco, CarlosPané, SalvadorPuigmartí Luis, JosepZamora Abanades, Félix JuanFischer, Peter3D printingCovalent organic frameworksInksProcessingQuímicaCovalent organic frameworks (COFs) have witnessed outstanding developments in the past 15 years, particularly in optimizing their pore structures, linkages, and variety of monomers used in their synthesis. Yet, a significant challenge remains unaddressed: the processability of COFs into macroscopic architectures with arbitrary shapes, as they are typically obtained as unprocessable powders. This study presents a novel strategy to address this issue by developing a 3D printable ink comprising a colloidal water suspension of COF nanoparticles. A microfluidic device is engineered that provides precise control over the gelation process of the COF-based ink, allowing for a layer-by-layer fabrication. As a result, the direct production of large-scale binder-free COF architectures from digital designs is achieved at room temperature and atmospheric pressure while eliminating the use of toxic organic solventsThis work had been supported by the Spanish MINECO (PID2019- 106268GB-C32, PID2022-138908NB-C31, TED2021-129886B-C42, PDC2022-133498-I00, and PID2020-116612RB-C33). The authors acknowledge the service from the MiNa Laboratory at IMN and funding from CM (project S2018/NMT-4291 TEC2SPACE), MINECO (project CSIC13-4E-1794) and EU (FEDER, FSE). F.Z. acknowledges financial support from the Spanish Ministry of Science and Innovation, through the “María de Maeztu” Programme for Units of Excellence in R&D (CEX2018- 000805-M). S.P., J.P.-L., and F. Z. also acknowledge support from the European Innovation Council under grant Agreement 101047081 (EVA). The authors acknowledge the support from the “(MAD2D-CM)-UAM” project funded by Comunidad de Madrid, by the Recovery, Transformation and Resilience Plan, and by NextGenerationEU from the European UnionWileyDepartamento de Química InorgánicaFacultad de Ciencias20232023-12-21research articlehttp://purl.org/coar/resource_type/c_2df8fbb1VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/710239https://dx.doi.org/10.1002/adfm.202314634reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/7102392026-06-23T12:46:27Z
dc.title.none.fl_str_mv 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths
title 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths
spellingShingle 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths
Royuela Collado, Sergio
3D printing
Covalent organic frameworks
Inks
Processing
Química
title_short 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths
title_full 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths
title_fullStr 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths
title_full_unstemmed 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths
title_sort 3D printing of covalent organic frameworks: a microfluidic-based system to manufacture binder-free macroscopic monoliths
dc.creator.none.fl_str_mv Royuela Collado, Sergio
Sevim, Semih
Hernanz, Guillermo
Rodríguez San Miguel, David
Franco, Carlos
Pané, Salvador
Puigmartí Luis, Josep
Zamora Abanades, Félix Juan
Fischer, Peter
author Royuela Collado, Sergio
author_facet Royuela Collado, Sergio
Sevim, Semih
Hernanz, Guillermo
Rodríguez San Miguel, David
Franco, Carlos
Pané, Salvador
Puigmartí Luis, Josep
Zamora Abanades, Félix Juan
Fischer, Peter
author_role author
author2 Sevim, Semih
Hernanz, Guillermo
Rodríguez San Miguel, David
Franco, Carlos
Pané, Salvador
Puigmartí Luis, Josep
Zamora Abanades, Félix Juan
Fischer, Peter
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Química Inorgánica
Facultad de Ciencias
dc.subject.none.fl_str_mv 3D printing
Covalent organic frameworks
Inks
Processing
Química
topic 3D printing
Covalent organic frameworks
Inks
Processing
Química
description Covalent organic frameworks (COFs) have witnessed outstanding developments in the past 15 years, particularly in optimizing their pore structures, linkages, and variety of monomers used in their synthesis. Yet, a significant challenge remains unaddressed: the processability of COFs into macroscopic architectures with arbitrary shapes, as they are typically obtained as unprocessable powders. This study presents a novel strategy to address this issue by developing a 3D printable ink comprising a colloidal water suspension of COF nanoparticles. A microfluidic device is engineered that provides precise control over the gelation process of the COF-based ink, allowing for a layer-by-layer fabrication. As a result, the direct production of large-scale binder-free COF architectures from digital designs is achieved at room temperature and atmospheric pressure while eliminating the use of toxic organic solvents
publishDate 2023
dc.date.none.fl_str_mv 2023
2023-12-21
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/710239
https://dx.doi.org/10.1002/adfm.202314634
url http://hdl.handle.net/10486/710239
https://dx.doi.org/10.1002/adfm.202314634
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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