Sequential formation of N-doped nanohelicenes, nanographenes and nanodomes by surface-assisted chemical (cyclo)dehydrogenation of heteroaromatics

We report on the stepwise formation of N-doped nanohelicenes, nanographenes, nanodomes and graphenes from the same heteroaromatic precursor through subsequent dehydrogenations on Pt(111) upon thermal annealing. The combined experimental (UHV-STM) and computational (DFT) studies provide a full atomis...

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Detalhes bibliográficos
Autores: Pinardi, Anna Lisa, Martínez, José I., López, María Francisca, Méndez, Javier, Martín-Gago, José A.
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2014
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/95339
Acesso em linha:http://hdl.handle.net/10261/95339
Access Level:acceso abierto
Descrição
Resumo:We report on the stepwise formation of N-doped nanohelicenes, nanographenes, nanodomes and graphenes from the same heteroaromatic precursor through subsequent dehydrogenations on Pt(111) upon thermal annealing. The combined experimental (UHV-STM) and computational (DFT) studies provide a full atomistic description of the intermediate reaction stages. This journal is © The Royal Society of Chemistry.

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