Recycling fiber-reinforced polyamide waste from the automotive industry: Life Cycle Assessment (LCA) of an advanced pyrolysis process to reclaim glass fibers and valuable chemicals

The generation of pyrolysis liquids and gases with poor quality is a limiting factor for the development of the recycling process of fiber-reinforced plastic waste. In this article, the life cycle assessment (LCA) of an advanced two-step pyrolysis process to recycle glass fiber-reinforced polyamide...

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Detalles Bibliográficos
Autores: Caballero Iglesias, Blanca María, López Urionabarrenechea, Alexander, González Arcos, Jean Paul, Pérez Martínez, Borja Baltasar, Acha Peña, Esther, Iturrondobeitia Ellacuria, Maider, Ibarretxe Uriguen, Julen, Esnaola, Aritz, Baskaran, Maider
Tipo de recurso: artículo
Fecha de publicación:2025
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/76752
Acceso en línea:http://hdl.handle.net/10810/76752
Access Level:acceso abierto
Palabra clave:glass mat-reinforced thermoplastic
automotive plastics
complex plastic waste
polyamide
pyrolysis
recycling
recycled glass fibers
life cycle assessment
Descripción
Sumario:The generation of pyrolysis liquids and gases with poor quality is a limiting factor for the development of the recycling process of fiber-reinforced plastic waste. In this article, the life cycle assessment (LCA) of an advanced two-step pyrolysis process to recycle glass fiber-reinforced polyamide waste is presented. First, the solid waste is pyrolyzed by heating up at 3 °C/min to 500 °C in a tank reactor. The generated volatiles are subsequently thermally cracked at 900 °C in a tubular packed bed reactor. The process is able to reclaim the glass fibers similarly to the conventional one reactor pyrolysis, while producing liquids and gases with better properties. The large quantity of oxygenated pyrolysis oils generated in the conventional pyrolysis are cracked into gaseous hydrocarbons, CO, CO2 and a minor aqueous liquid. The pyrolysis gases become the main product of the process, presenting an interesting composition of hydrogen (39.9 vol.%), methane (22.5 vol.%), carbon monoxide (19.5 vol.%) and ethylene (10.8 vol.%). The LCA shows that advanced pyrolysis demonstrates better environmental performance than conventional pyrolysis, avoiding fossil resource scarcity and reducing global warming by half and human carcinogenic toxicity by one third.