Hybrid tellurium-lignin nanoparticles with enhanced antibacterial properties

The surge of antibiotic-resistant bacteria is leading to the loss of antibiotic treatment effectiveness, resulting in prolonged infections and even death. Against this healthcare threat, antimicrobial nanoparticles that hamper the evolve of resistance mechanisms are promising alternatives to antibio...

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Detalhes bibliográficos
Autores: Morena Gatius, Ángela Gala|||0000-0003-4470-8249, Bassegoda Puigdomenech, Arnau, Hoyo Pérez, Javier|||0000-0002-9927-2465, Tzanov, Tzanko|||0000-0002-8568-1110
Formato: artículo
Fecha de publicación:2021
País:España
Recursos:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/344082
Acesso em linha:https://hdl.handle.net/2117/344082
https://dx.doi.org/10.1021/acsami.0c22301
Access Level:acceso abierto
Palavra-chave:Nanoparticles
Lignin
Tellurium
Hybrid nanoparticles
Sonochemistry
Antibacterial activity
Green synthesis
Nanopartícules
Àrees temàtiques de la UPC::Enginyeria química
Descrição
Resumo:The surge of antibiotic-resistant bacteria is leading to the loss of antibiotic treatment effectiveness, resulting in prolonged infections and even death. Against this healthcare threat, antimicrobial nanoparticles that hamper the evolve of resistance mechanisms are promising alternatives to antibiotics. Herein, we used Kraft lignin, a poorly valorized polymer derived from plant biomass, to develop novel hybrid tellurium-lignin nanoparticles (TeLigNPs) as alternative antimicrobial agents. The sonochemically synthesized TeLigNPs are comprised of a lignin matrix with embedded Te clusters, revealing the role of lignin as both reducing agent and structural component. The hybrid NPs showed strong bactericidal effect against the Gram-negative Escherichia coli and Pseudomonas aeruginosa, achieving more than 5 log bacteria reduction, while only slightly inhibited the growth of the Gram-positive Staphylococcus aureus. Exposure of TeLigNPs to human cells did not cause morphological changes or reduction in cell viability. Studies on the antimicrobial mechanism of action demonstrated that the novel TeLigNPs were able to disturb bacterial model membranes and generate reactive oxygen species (ROS) in Gram-negative bacteria.