Direct mass spectrometry-based approaches in metabolomics

Metabolomics is one of the newest Omics technologies concerned with the identification and quantification of small molecules in a high-throughput manner. Considering the number of different types of metabolites present in a wide dynamic range of concentrations in any single living system, actual ana...

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Bibliographic Details
Authors: Ibáñez, Clara, García-Cañas, Virginia, Valdés, Alberto, Simó, Carolina
Format: other
Status:Versión aceptada para publicación
Publication Date:2014
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/99917
Online Access:http://hdl.handle.net/10261/99917
Access Level:Open access
Keyword:DESI
SIMS
MALDI
Ambient MS
DART
Imaging MS
NIMS
Mass spectrometry
Description
Summary:Metabolomics is one of the newest Omics technologies concerned with the identification and quantification of small molecules in a high-throughput manner. Considering the number of different types of metabolites present in a wide dynamic range of concentrations in any single living system, actual analytical technologies can still only capture a part of the metabolome. Currently, MS-based approaches yield a higher sensitivity than NMR when analyzing minimal amounts of complex mixtures. Most MS-based approaches in metabolomics involve a physical/chemical purification/fractionation prior to MS analysis, to avoid sample matrix effects, at the expense of low high-throughput performance. In the quest to achieve the maximum high-throughput production of metabolite information in the largest possible number of samples, an extensive array of direct ionization or desorption/ionization techniques have been developed and combined. In the this chapter, an overview of the main desorption/ionization techniques coupled with MS applied to direct metabolite profiling or fingerprinting is presented. © 2014 Elsevier B.V.