Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2
Use of copper wire bits as simple catalyst in a click chemistry reaction using supercritical CO2 has been achieved. The use of this catalyst in the reaction between polylactic acid (PLA) and coumarin allows to remove the whole amount of catalyst in the final product with a simple purification step u...
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2020 |
| País: | España |
| Institución: | Universidad de Castilla-La Mancha |
| Repositorio: | RUIdeRA. Repositorio Institucional de la UCLM |
| OAI Identifier: | oai:ruidera.uclm.es:10578/29958 |
| Acceso en línea: | http://hdl.handle.net/10578/29958 |
| Access Level: | acceso abierto |
| Palabra clave: | Click chemistry Supercritical CO2 Copper wire Polymer functionalization CO2 supercrítico Alambre de cobres Funcionalización de polímero |
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Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2Gracia, EulalioGarcía González, María TeresaLucas Martínez, Antonio deRodríguez Romero, Juan FranciscoGracia Fernández, IgnacioClick chemistrySupercritical CO2Copper wirePolymer functionalizationCO2 supercríticoAlambre de cobresFuncionalización de polímeroUse of copper wire bits as simple catalyst in a click chemistry reaction using supercritical CO2 has been achieved. The use of this catalyst in the reaction between polylactic acid (PLA) and coumarin allows to remove the whole amount of catalyst in the final product with a simple purification step using a green solvent where no toxic solvent is used in order to synthetize the product.Se ha logrado el uso de brocas de alambre de cobre como catalizador simple en una reacción química clic usando CO2 supercrítico . El uso de este catalizador en la reacción entre el ácido poliláctico (PLA) y la cumarina permite eliminar la cantidad total de catalizador en el producto final con un simple paso de purificación usando un solvente verde donde no se usa ningún solvente tóxico para sintetizar el producto.Elsevier202220222020info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttp://hdl.handle.net/10578/29958reponame:RUIdeRA. Repositorio Institucional de la UCLMinstname:Universidad de Castilla-La ManchaInglésinfo:eu-repo/semantics/openAccessoai:ruidera.uclm.es:10578/299582026-05-27T07:36:41Z |
| dc.title.none.fl_str_mv |
Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2 |
| title |
Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2 |
| spellingShingle |
Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2 Gracia, Eulalio Click chemistry Supercritical CO2 Copper wire Polymer functionalization CO2 supercrítico Alambre de cobres Funcionalización de polímero |
| title_short |
Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2 |
| title_full |
Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2 |
| title_fullStr |
Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2 |
| title_full_unstemmed |
Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2 |
| title_sort |
Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2 |
| dc.creator.none.fl_str_mv |
Gracia, Eulalio García González, María Teresa Lucas Martínez, Antonio de Rodríguez Romero, Juan Francisco Gracia Fernández, Ignacio |
| author |
Gracia, Eulalio |
| author_facet |
Gracia, Eulalio García González, María Teresa Lucas Martínez, Antonio de Rodríguez Romero, Juan Francisco Gracia Fernández, Ignacio |
| author_role |
author |
| author2 |
García González, María Teresa Lucas Martínez, Antonio de Rodríguez Romero, Juan Francisco Gracia Fernández, Ignacio |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
Click chemistry Supercritical CO2 Copper wire Polymer functionalization CO2 supercrítico Alambre de cobres Funcionalización de polímero |
| topic |
Click chemistry Supercritical CO2 Copper wire Polymer functionalization CO2 supercrítico Alambre de cobres Funcionalización de polímero |
| description |
Use of copper wire bits as simple catalyst in a click chemistry reaction using supercritical CO2 has been achieved. The use of this catalyst in the reaction between polylactic acid (PLA) and coumarin allows to remove the whole amount of catalyst in the final product with a simple purification step using a green solvent where no toxic solvent is used in order to synthetize the product. |
| publishDate |
2020 |
| dc.date.none.fl_str_mv |
2020 2022 2022 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10578/29958 |
| url |
http://hdl.handle.net/10578/29958 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf application/pdf |
| dc.publisher.none.fl_str_mv |
Elsevier |
| publisher.none.fl_str_mv |
Elsevier |
| dc.source.none.fl_str_mv |
reponame:RUIdeRA. Repositorio Institucional de la UCLM instname:Universidad de Castilla-La Mancha |
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Universidad de Castilla-La Mancha |
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RUIdeRA. Repositorio Institucional de la UCLM |
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RUIdeRA. Repositorio Institucional de la UCLM |
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1869407197025271808 |
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15,301603 |