Copper wire as a clean and efficient catalyst for click chemistry in supercritical CO2

Use of copper wire bits as simple catalyst in a click chemistry reaction using supercritical CO2 has been achieved. The use of this catalyst in the reaction between polylactic acid (PLA) and coumarin allows to remove the whole amount of catalyst in the final product with a simple purification step u...

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Detalles Bibliográficos
Autores: Gracia, Eulalio, García González, María Teresa, Lucas Martínez, Antonio de, Rodríguez Romero, Juan Francisco, Gracia Fernández, Ignacio
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/29958
Acceso en línea:http://hdl.handle.net/10578/29958
Access Level:acceso abierto
Palabra clave:Click chemistry
Supercritical CO2
Copper wire
Polymer functionalization
CO2 supercrítico
Alambre de cobres
Funcionalización de polímero
Descripción
Sumario:Use of copper wire bits as simple catalyst in a click chemistry reaction using supercritical CO2 has been achieved. The use of this catalyst in the reaction between polylactic acid (PLA) and coumarin allows to remove the whole amount of catalyst in the final product with a simple purification step using a green solvent where no toxic solvent is used in order to synthetize the product.