Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observe...

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Autores: Sánchez Mellado, Práxedes, Hernández Juárez, Martín, Rendón Márquez, Nuria, López Serrano, Joaquín, López Santos, Laura, Álvarez González, Eleuterio, Paneque Sosa, Margarita, Suárez Escobar, Andrés Luis
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/136998
Acceso en línea:https://hdl.handle.net/11441/136998
https://doi.org/10.1039/d0dt02326d
Access Level:acceso abierto
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repository_id_str
spelling Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligandsSánchez Mellado, PráxedesHernández Juárez, MartínRendón Márquez, NuriaLópez Serrano, JoaquínLópez Santos, LauraÁlvarez González, EleuterioPaneque Sosa, MargaritaSuárez Escobar, Andrés LuisRu complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions.(FEDER contribution) from the Spanish Ministry of Science and Innovation (CTQ2016-80814-R)Junta de Andalucía (PY18-3208)Royal Society of ChemistryQuímica InorgánicaEuropean Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER)Ministerio de Ciencia e Innovación (MICIN). EspañaJunta de Andalucía2020info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/136998https://doi.org/10.1039/d0dt02326dreponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésDalton Transactions, 49 (28), 9583-9587.CTQ2016-80814-RPY18-3208https://dx.doi.org/10.1039/d0dt02326dinfo:eu-repo/semantics/openAccessoai:idus.us.es:11441/1369982026-06-17T12:51:07Z
dc.title.none.fl_str_mv Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
title Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
spellingShingle Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
Sánchez Mellado, Práxedes
title_short Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
title_full Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
title_fullStr Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
title_full_unstemmed Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
title_sort Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
dc.creator.none.fl_str_mv Sánchez Mellado, Práxedes
Hernández Juárez, Martín
Rendón Márquez, Nuria
López Serrano, Joaquín
López Santos, Laura
Álvarez González, Eleuterio
Paneque Sosa, Margarita
Suárez Escobar, Andrés Luis
author Sánchez Mellado, Práxedes
author_facet Sánchez Mellado, Práxedes
Hernández Juárez, Martín
Rendón Márquez, Nuria
López Serrano, Joaquín
López Santos, Laura
Álvarez González, Eleuterio
Paneque Sosa, Margarita
Suárez Escobar, Andrés Luis
author_role author
author2 Hernández Juárez, Martín
Rendón Márquez, Nuria
López Serrano, Joaquín
López Santos, Laura
Álvarez González, Eleuterio
Paneque Sosa, Margarita
Suárez Escobar, Andrés Luis
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Química Inorgánica
European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER)
Ministerio de Ciencia e Innovación (MICIN). España
Junta de Andalucía
description Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions.
publishDate 2020
dc.date.none.fl_str_mv 2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/136998
https://doi.org/10.1039/d0dt02326d
url https://hdl.handle.net/11441/136998
https://doi.org/10.1039/d0dt02326d
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Dalton Transactions, 49 (28), 9583-9587.
CTQ2016-80814-R
PY18-3208
https://dx.doi.org/10.1039/d0dt02326d
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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