Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observe...

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Detalles Bibliográficos
Autores: Sánchez Mellado, Práxedes, Hernández Juárez, Martín, Rendón Márquez, Nuria, López Serrano, Joaquín, López Santos, Laura, Álvarez González, Eleuterio, Paneque Sosa, Margarita, Suárez Escobar, Andrés Luis
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/136998
Acceso en línea:https://hdl.handle.net/11441/136998
https://doi.org/10.1039/d0dt02326d
Access Level:acceso abierto
Descripción
Sumario:Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions.

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