Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million...

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Autores: Manzini, Simone, Cavallo, Luigi, Nolan, Steven P., Urbina-Blanco, Cesar A., Nelson, David J., Poater Teixidor, Albert, Lebl, Tomas, Meiries, Sébastien, Slawin, Alexandra M. Z., Falivene, Laura
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/13286
Acceso en línea:http://hdl.handle.net/10256/13286
Access Level:acceso abierto
Palabra clave:Funcional de densitat, Teoria del
Density functionals
Metàtesi (Química)
Metathesis (Chemistry)
Ruteni
Ruthenium
Alquens
Alkenes
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spelling Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbeneManzini, SimoneCavallo, LuigiNolan, Steven P.Urbina-Blanco, Cesar A.Nelson, David J.Poater Teixidor, AlbertLebl, TomasMeiries, SébastienSlawin, Alexandra M. Z.Falivene, LauraFuncional de densitat, Teoria delDensity functionalsMetàtesi (Química)Metathesis (Chemistry)RuteniRutheniumAlquensAlkenesThe commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been exploredSPN thanks the European Research Council (227817) (Advanced Investigator Award ‘FUNCAT’), the EU (CP-FP 211468) (Seventh Framework Programme Project ‘EUMET’), and the Engineering and Physical Sciences Research Council for funding. SPN is a Royal Society Wolfson Merit Award holder. AP thanks the Spanish MINECO for a Ram on y Cajal contract (RYC-2009-05226) and European Commission for a Career Integration Grant (CIG09-GA-2011- 293900)ElsevierMinisterio de Economía y Competitividad (Espanya)2015info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionpeer-reviewedapplication/pdfhttp://hdl.handle.net/10256/13286http://hdl.handle.net/10256/13286© Journal of Organometallic Chemistry, 2015, vol. 780, p. 43-48Articles publicats (D-Q)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jorganchem.2014.12.040info:eu-repo/semantics/altIdentifier/issn/0022-328Xinfo:eu-repo/grantAgreement/MICINN//RYC-2009-05226info:eu-repo/grantAgreement/EC/FP7/293900Tots els drets reservatsinfo:eu-repo/semantics/openAccessoai:recercat.cat:10256/132862026-05-29T05:05:01Z
dc.title.none.fl_str_mv Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
title Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
spellingShingle Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
Manzini, Simone
Funcional de densitat, Teoria del
Density functionals
Metàtesi (Química)
Metathesis (Chemistry)
Ruteni
Ruthenium
Alquens
Alkenes
title_short Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
title_full Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
title_fullStr Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
title_full_unstemmed Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
title_sort Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
dc.creator.none.fl_str_mv Manzini, Simone
Cavallo, Luigi
Nolan, Steven P.
Urbina-Blanco, Cesar A.
Nelson, David J.
Poater Teixidor, Albert
Lebl, Tomas
Meiries, Sébastien
Slawin, Alexandra M. Z.
Falivene, Laura
author Manzini, Simone
author_facet Manzini, Simone
Cavallo, Luigi
Nolan, Steven P.
Urbina-Blanco, Cesar A.
Nelson, David J.
Poater Teixidor, Albert
Lebl, Tomas
Meiries, Sébastien
Slawin, Alexandra M. Z.
Falivene, Laura
author_role author
author2 Cavallo, Luigi
Nolan, Steven P.
Urbina-Blanco, Cesar A.
Nelson, David J.
Poater Teixidor, Albert
Lebl, Tomas
Meiries, Sébastien
Slawin, Alexandra M. Z.
Falivene, Laura
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (Espanya)
dc.subject.none.fl_str_mv Funcional de densitat, Teoria del
Density functionals
Metàtesi (Química)
Metathesis (Chemistry)
Ruteni
Ruthenium
Alquens
Alkenes
topic Funcional de densitat, Teoria del
Density functionals
Metàtesi (Química)
Metathesis (Chemistry)
Ruteni
Ruthenium
Alquens
Alkenes
description The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored
publishDate 2015
dc.date.none.fl_str_mv 2015
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
peer-reviewed
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/13286
http://hdl.handle.net/10256/13286
url http://hdl.handle.net/10256/13286
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jorganchem.2014.12.040
info:eu-repo/semantics/altIdentifier/issn/0022-328X
info:eu-repo/grantAgreement/MICINN//RYC-2009-05226
info:eu-repo/grantAgreement/EC/FP7/293900
dc.rights.none.fl_str_mv Tots els drets reservats
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Tots els drets reservats
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv © Journal of Organometallic Chemistry, 2015, vol. 780, p. 43-48
Articles publicats (D-Q)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,81155

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