Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million...

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Detalles Bibliográficos
Autores: Manzini, Simone, Cavallo, Luigi, Nolan, Steven P., Urbina-Blanco, Cesar A., Nelson, David J., Poater Teixidor, Albert, Lebl, Tomas, Meiries, Sébastien, Slawin, Alexandra M. Z., Falivene, Laura
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/13286
Acceso en línea:http://hdl.handle.net/10256/13286
Access Level:acceso abierto
Palabra clave:Funcional de densitat, Teoria del
Density functionals
Metàtesi (Química)
Metathesis (Chemistry)
Ruteni
Ruthenium
Alquens
Alkenes
Descripción
Sumario:The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored

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