Effect of oxidized wood flour as functional filler on the mechanical, thermal and flame-retardant properties of polylactide biocomposites
Based on the biodegradable material-polyethylene glycol (PEG)-as the plasticizer, oxidized wood flour (OWF) as the charring agent for polylactide (PLA), a series flame-retardant PLA biocomposites were prepared via melt-compounding and hot-compression. The effect of OWF on the thermal, mechanical and...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Universitat Politècnica de Catalunya (UPC) |
| Repositorio: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglés |
| OAI Identifier: | oai:upcommons.upc.edu:2117/129521 |
| Acceso en línea: | https://hdl.handle.net/2117/129521 https://dx.doi.org/10.1016/j.indcrop.2018.12.090 |
| Access Level: | acceso abierto |
| Palabra clave: | Polylactic acid Àcid polilàctic Àrees temàtiques de la UPC::Edificació::Materials de construcció::Nous materials de construcció |
| Sumario: | Based on the biodegradable material-polyethylene glycol (PEG)-as the plasticizer, oxidized wood flour (OWF) as the charring agent for polylactide (PLA), a series flame-retardant PLA biocomposites were prepared via melt-compounding and hot-compression. The effect of OWF on the thermal, mechanical and flame retardant properties of biocomposites was investigated systemically. We have found that after the incorporation of PEG and OWF with 10¿wt% into PLA, the biocomposite showed higher tensile elongation than pure PLA. Furthermore, the presence of OWF and ammonium polyphosphate (APP) imparted the biocomposite good flame-retardant performance, shown a remarkable reduction on the peak of heat release rate (PHRR), improved LOI value and passed UL94 V-0 rating. Moreover, Scanning electron microscopy-energy dispersive spectra (SEM/EDS) and thermogravimetric analysis coupled with infrared spectrometer (TG-FTIR) were also performed to understand the flame retardant mechanism. These results proved that OWF could be as new functional filler for polymer composites to further improve their flame retardancy. |
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