Highly enantioselective imine hydrogenation catalyzed by ruthenium phosphane-phosphite diamine complexes

Mildly does it: A highly enantioselective catalyst for the hydrogenation of N-aryl imines is described (see scheme). This catalyst offers practical advantages because it operates under very mild conditions and is based on an Ru complex with a diamine as the sole chiral ligand.

Detalhes bibliográficos
Autores: Vaquero Gutiérrez, Mónica, Suárez Escobar, Andrés Luis, Vargas Rodríguez, Sergio, Bottari, Giovanni, Álvarez González, Eleuterio, Pizzano Mancera, Antonio
Tipo de documento: artigo
Estado:Versión enviada para evaluación y publicación
Data de publicação:2012
País:España
Recursos:Universidad de Sevilla (US)
Repositório:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/71034
Acesso em linha:https://hdl.handle.net/11441/71034
https://doi.org/10.1002/chem.201203193
Access Level:Acceso aberto
Palavra-chave:P-ligands
Imines
Hydrogenation
Asymmetric catalysis
Ruthenium
Descrição
Resumo:Mildly does it: A highly enantioselective catalyst for the hydrogenation of N-aryl imines is described (see scheme). This catalyst offers practical advantages because it operates under very mild conditions and is based on an Ru complex with a diamine as the sole chiral ligand.