Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes

The presence of tetrazine units in the organic nodes of UiO-68-TZCD controls the formation of ultrathin coatings of single-wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the properti...

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Autores: Lerma-Berlanga, Belén, Padial, Natalia M., Galbiati, Marta, Brotons-Alcázar, Isaac, Albero, J., García Gómez, Hermenegildo, Forment-Aliaga, Alicia, Ganivet, Carolina R., Martí-Gastaldo, Carlos
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/352200
Acceso en línea:http://hdl.handle.net/10261/352200
Access Level:acceso abierto
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spelling Wrapping up Metal–Organic Framework Crystals with Carbon NanotubesLerma-Berlanga, BelénPadial, Natalia M.Galbiati, MartaBrotons-Alcázar, IsaacAlbero, J.García Gómez, HermenegildoForment-Aliaga, AliciaGanivet, Carolina R.Martí-Gastaldo, CarlosThe presence of tetrazine units in the organic nodes of UiO-68-TZCD controls the formation of ultrathin coatings of single-wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the properties of the framework for combination of mesoporosity and surface areas ≈4.000 m g, with excellent stability in water, and conductivities at room temperature of 4 × 10 S cm even at very low carbon weight contents (2.3 wt.%).B.L.-B. and N.M.P. contributed equally to the work. This work was supported by the EU H2020 program (ERC-2021-COG-101043428 & ERC-2016-STG-714122), the Generalitat Valenciana (PROMETEU/2021/054 and SEJIGENT/2021/059) and the Spanish government (CEX2019-000919-M, PID2020-118117RB-I00 & EUR2021-121999). B.L.-B. thanks the Spanish government for an FPU (FPU16/04162). N.M.P. and M.G. thanks La Caixa Foundation for a Postdoctoral Junior Leader–Retaining Fellowship (ID 100010434 & ID 100010434 and fellowship code LCF/BQ/PR20/11770014 & LCF/BQ/PR21/11840011). The authors also thank the University of Valencia for its research facilities (NANBIOSIS). J.A. and H. G. are grateful to the Spanish Ministry of Science and Innovation (RTI2018-98237-CO2-1) and Generalitat Valenciana (Prometeo 2021–038) for the financial support.With funding from the Spanish government through the ‘Severo Ochoa Centre of Excellence’ accreditation (CEX2019-000919-M).Peer reviewedJohn Wiley & SonsMinisterio de Ciencia e Innovación (España)European CommissionGeneralitat ValencianaAgencia Estatal de Investigación (España)Ministerio de Ciencia, Innovación y Universidades (España)Universidad de ValenciaGeneralitat ValencianaConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2024202420232024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/352200reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/101043428info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2019-000919-Minfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-118117RB-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C22http://dx.doi.org/10.1002/adfm.202302246Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3522002026-05-22T06:33:51Z
dc.title.none.fl_str_mv Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes
title Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes
spellingShingle Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes
Lerma-Berlanga, Belén
title_short Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes
title_full Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes
title_fullStr Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes
title_full_unstemmed Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes
title_sort Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes
dc.creator.none.fl_str_mv Lerma-Berlanga, Belén
Padial, Natalia M.
Galbiati, Marta
Brotons-Alcázar, Isaac
Albero, J.
García Gómez, Hermenegildo
Forment-Aliaga, Alicia
Ganivet, Carolina R.
Martí-Gastaldo, Carlos
author Lerma-Berlanga, Belén
author_facet Lerma-Berlanga, Belén
Padial, Natalia M.
Galbiati, Marta
Brotons-Alcázar, Isaac
Albero, J.
García Gómez, Hermenegildo
Forment-Aliaga, Alicia
Ganivet, Carolina R.
Martí-Gastaldo, Carlos
author_role author
author2 Padial, Natalia M.
Galbiati, Marta
Brotons-Alcázar, Isaac
Albero, J.
García Gómez, Hermenegildo
Forment-Aliaga, Alicia
Ganivet, Carolina R.
Martí-Gastaldo, Carlos
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
European Commission
Generalitat Valenciana
Agencia Estatal de Investigación (España)
Ministerio de Ciencia, Innovación y Universidades (España)
Universidad de Valencia
Generalitat Valenciana
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description The presence of tetrazine units in the organic nodes of UiO-68-TZCD controls the formation of ultrathin coatings of single-wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the properties of the framework for combination of mesoporosity and surface areas ≈4.000 m g, with excellent stability in water, and conductivities at room temperature of 4 × 10 S cm even at very low carbon weight contents (2.3 wt.%).
publishDate 2023
dc.date.none.fl_str_mv 2023
2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/352200
url http://hdl.handle.net/10261/352200
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/H2020/101043428
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2019-000919-M
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-118117RB-I00
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-098237-B-C22
http://dx.doi.org/10.1002/adfm.202302246
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
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