Structural and physico-mechanical properties of natural rubber/GTR composites devulcanized by microwaves: influence of GTR source and irradiation time

Ground tire rubber from car and truck was modified using microwave irradiation at variable time. The irradiated ground tire rubber was used as filler in composites based on natural rubber. The composites, with high content of ground tire rubber, were prepared using an internal batch mixer and subseq...

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Bibliographic Details
Authors: Colom Fajula, Xavier|||0000-0003-3511-852X, Marin-Genesca, Marc, Mujal-Rosas, Ramon Maria|||0000-0001-6859-8318, Formela, Krzysztof, Cañavate Ávila, Francisco Javier|||0000-0002-1502-6962
Format: article
Publication Date:2018
Country:España
Institution:Universitat Politècnica de Catalunya (UPC)
Repository:UPCommons. Portal del coneixement obert de la UPC
Language:English
OAI Identifier:oai:upcommons.upc.edu:2117/116175
Online Access:https://hdl.handle.net/2117/116175
https://dx.doi.org/10.1177/0021998318761554
Access Level:Open access
Keyword:Rubber
Tires--Recycling
Rubber, Reclaimed
Materials--Mechanical properties
Recycling
Ground tire rubber
Microwave irradiation
Natural rubber
Mechanical properties
Cautxú -- Reciclatge
Cautxú -- Reutilització
Pneumàtics -- Reciclatge
Materials -- Propietats mecàniques
Description
Summary:Ground tire rubber from car and truck was modified using microwave irradiation at variable time. The irradiated ground tire rubber was used as filler in composites based on natural rubber. The composites, with high content of ground tire rubber, were prepared using an internal batch mixer and subsequently cross-linked at 160¿. The influence of the ground tire rubber source (car/truck) and irradiation time on structure, physico-mechanical behaviour, thermal properties and morphology of natural rubber/ground tire rubber composites was studied. The interfacial interactions between ground tire rubber and natural rubber as function of ground tire rubber source and irradiation time were evaluated by Fourier transform infrared spectroscopy, thermogravimetric analysis, tensile tests, swelling measurements and scanning electron microscopy. The results showed that irradiation of ground tire rubber slightly enhanced tensile properties and cross-link density of natural rubber/ground tire rubber composites. This effect was more evident in the case of ground tire rubbertruck because of its higher content of natural rubber and was reflected in changes in the interfacial adhesion, which were confirmed by the results of Fourier transform infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy analysis