Sc3N@Ih-C80 based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation

Light induced charge separation in a newly synthesized triphenylamine–thiophene-Sc3N@Ih-C80 donor–acceptor conjugate and its C60 analog, triphenylamine–thiophene-C60 conjugate is reported, and the significance of the thiophene spacer in promoting electron transfer events is unraveled.

Detalles Bibliográficos
Autores: Caballero Briceño, Rubén, Servian Rivas, Luis David, Gobeze, Habtom, Fernandez-Delgado, Olivia, Echegoyen, Luis, D'Souza, Francis, Gómez-Escalonilla Romojaro, María José
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/28986
Acceso en línea:http://hdl.handle.net/10578/28986
Access Level:acceso abierto
Palabra clave:new donor–acceptor conjugates
thiophene spacer
Sc3N@Ih-C80
Descripción
Sumario:Light induced charge separation in a newly synthesized triphenylamine–thiophene-Sc3N@Ih-C80 donor–acceptor conjugate and its C60 analog, triphenylamine–thiophene-C60 conjugate is reported, and the significance of the thiophene spacer in promoting electron transfer events is unraveled.

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