Visible-light mediated regioselective chlorosulfonylation of acrylamides

Herein, a one-step chlorosulfonylation of acrylamides via a photocatalytic redox process is described. This reaction provides ?-chlorosulfonylamides with a quaternary center with high regioselectivity via radical process. It is amenable to a broad range of substrates and the products are obtained in...

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Detalhes bibliográficos
Autores: Merino Marcos, Estíbaliz|||0000-0002-2960-5404, Zurro de la Fuente, Mercedes|||0000-0003-1222-7926, Otárola Tejada, Guillermo Germán|||0000-0003-1367-3127, Vaquero López, Juan José|||0000-0002-3820-9673, Torres Oya, Sergio|||0000-0002-1003-519X
Formato: artículo
Fecha de publicación:2023
País:España
Recursos:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/56270
Acesso em linha:http://hdl.handle.net/10017/56270
https://dx.doi.org/10.1055/s-0042-1751424
Access Level:acceso abierto
Palavra-chave:Acrylamides
difunctionalization of alkenes
photocatalysis
chlorosulfonylation
alfa-chloro sulfones
Química
Chemistry
Descrição
Resumo:Herein, a one-step chlorosulfonylation of acrylamides via a photocatalytic redox process is described. This reaction provides ?-chlorosulfonylamides with a quaternary center with high regioselectivity via radical process. It is amenable to a broad range of substrates and the products are obtained in moderate to good yields

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