Unraveling Thermal Interactions in Lanthanide-Doped Phosphors: A Frequency-Domain Analysis Approach [Dataset]
Ensuring the thermal reliability of luminescent materials is a key requirement for next-generation lighting, display, and sensing technologies. The intricate interplay of thermal crossover and thermal ionization in lanthanide-doped phosphors often obscures their individual contributions. We present...
| Autores: | , , , , |
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| Tipo de recurso: | conjunto de datos |
| Fecha de publicación: | 2026 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/420565 |
| Acceso en línea: | http://hdl.handle.net/10261/420565 https://doi.org/10.20350/digitalCSIC/18118 |
| Access Level: | acceso abierto |
| Palabra clave: | Persistent luminescence Afterglow Phosphors Thermal ionization Efficiency Thermal quenching Frequency analysis |
| Sumario: | Ensuring the thermal reliability of luminescent materials is a key requirement for next-generation lighting, display, and sensing technologies. The intricate interplay of thermal crossover and thermal ionization in lanthanide-doped phosphors often obscures their individual contributions. We present a frequency-domain photoluminescence analysis that disentangles these competing mechanisms. Using single crystals of SrAl₂O₄:Eu²⁺,Dy³⁺ (SAO:Eu,Dy) and (Gd₀.₃₃Y₀.₆₇)₃Al₂.₄Ga₂.₆O₁₂:Ce3+,Cr3+ (GYAGG:Ce,Cr) as model systems, we extract temperature-dependent trapping efficiencies and decay rates by analyzing the phase and amplitude response of luminescence under modulated excitation. Our approach reveals distinct signatures of thermal ionization and enables the direct quantification of ionization barriers and crossover rates. We demonstrate that SAO:Eu,Dy exhibits dominant trapping behavior with high ionization efficiency, while GYAGG:Ce,Cr shows significant competition between ionization and crossover. This method provides a powerful framework for resolving overlapping quenching pathways and offers new insights for the design of thermally robust luminescent materials. |
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