Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands
The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes p...
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad de Barcelona |
| Repositorio: | Dipòsit Digital de la UB |
| OAI Identifier: | oai:diposit.ub.edu:2445/68334 |
| Acceso en línea: | https://hdl.handle.net/2445/68334 |
| Access Level: | acceso abierto |
| Palabra clave: | Hidròlisi Lligands Catàlisi asimètrica Compostos de bor Hydrolysis Ligands Enantioselective catalysis Boron compounds |
| Sumario: | The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands. |
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