Catalytically Active Imine-based Covalent Organic Frameworks for Detoxification of Nerve Agent Simulants in Aqueous Media

A series of imine-based covalent organic frameworks decorated in their cavities with different alkynyl, pyrrolidine, and N-methylpyrrolidine functional groups have been synthetized. These materials exhibit catalytic activity in aqueous media for the hydrolytic detoxification of nerve agents, as exem...

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Detalles Bibliográficos
Autores: Royuela, Sergio, Gil-San Millán, Rodrigo, Mancheño Real, María José, Ramos, M. Mar, Segura Castedo, José Luis, Navarro, Jorge A. R., Zamora, Félix
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/12626
Acceso en línea:https://hdl.handle.net/20.500.14352/12626
Access Level:acceso abierto
Palabra clave:covalent organic frameworks
catalysis
chemical warfare agents
detoxification
Química orgánica (Química)
2306 Química Orgánica
Descripción
Sumario:A series of imine-based covalent organic frameworks decorated in their cavities with different alkynyl, pyrrolidine, and N-methylpyrrolidine functional groups have been synthetized. These materials exhibit catalytic activity in aqueous media for the hydrolytic detoxification of nerve agents, as exemplified with nerve gas simulant diisopropylfluorophosphate (DIFP). These preliminary results suggest imine-based covalent organic frameworks (COFs) as promising materials for detoxification of highly toxic molecules.