Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset]
Strong coupling between lead halide perovskite materials and optical resonators enables both the polaritonic control of the photophysical properties of these emerging semiconductors and the observation of novel fundamental physical phenomena. However, the difficulty to achieve optical-quality perovs...
| Autores: | , , , , , , , , |
|---|---|
| Tipo de recurso: | conjunto de datos |
| Fecha de publicación: | 2021 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/343100 |
| Acceso en línea: | http://hdl.handle.net/10261/343100 https://doi.org/10.20350/digitalCSIC/16079 |
| Access Level: | acceso abierto |
| Palabra clave: | Polaritons Optical Microcavities Quantum dot solids Perovskites Strong exciton-photon Coupling |
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Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset] |
| title |
Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset] |
| spellingShingle |
Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset] Bujalance, Clara Polaritons Optical Microcavities Quantum dot solids Perovskites Strong exciton-photon Coupling |
| title_short |
Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset] |
| title_full |
Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset] |
| title_fullStr |
Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset] |
| title_full_unstemmed |
Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset] |
| title_sort |
Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset] |
| dc.creator.none.fl_str_mv |
Bujalance, Clara Calió, Laura Dirin, Dmitry N. Tiede, David O. Galisteo-López, Juan F. Feist, Johannes García-Vidal, Francisco J. Kovalenko, Maksym V. Míguez, Hernán |
| author |
Bujalance, Clara |
| author_facet |
Bujalance, Clara Calió, Laura Dirin, Dmitry N. Tiede, David O. Galisteo-López, Juan F. Feist, Johannes García-Vidal, Francisco J. Kovalenko, Maksym V. Míguez, Hernán |
| author_role |
author |
| author2 |
Calió, Laura Dirin, Dmitry N. Tiede, David O. Galisteo-López, Juan F. Feist, Johannes García-Vidal, Francisco J. Kovalenko, Maksym V. Míguez, Hernán |
| author2_role |
author author author author author author author author |
| dc.contributor.none.fl_str_mv |
Ministerio de Ciencia e Innovación (España) Agencia Estatal de Investigación (España) European Commission Junta de Andalucía Air Force Office of Scientific Research (US) Office of Naval Research (US) Míguez, Hernán [0000-0003-2925-6360] Míguez, Hernán [h.miguez@csic.es] Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Polaritons Optical Microcavities Quantum dot solids Perovskites Strong exciton-photon Coupling |
| topic |
Polaritons Optical Microcavities Quantum dot solids Perovskites Strong exciton-photon Coupling |
| description |
Strong coupling between lead halide perovskite materials and optical resonators enables both the polaritonic control of the photophysical properties of these emerging semiconductors and the observation of novel fundamental physical phenomena. However, the difficulty to achieve optical-quality perovskite quantum dot (PQD) films showing well-defined excitonic transitions has prevented the study of strong light-matter coupling in these materials, central to the field of optoelectronics. Herein we demonstrate the formation at room temperature of multiple cavity exciton-polaritons in metallic resonators embedding highly transparent Cesium Lead Bromide quantum dot (CsPbBr3-QD) solids, revealed by a significant reconfiguration of the absorption and emission properties of the system. Our results indicate that the effects of biexciton interaction or large polaron formation, frequently invoked to explain the properties of PQDs, are seemingly absent or compensated by other more conspicuous effects in the CsPbBr3-QD optical cavity. We observe that strong coupling enables a significant reduction of the photoemission linewidth, as well as the ultrafast modulation of the optical absorption, controllable by means of the excitation fluence. We find that the interplay of the polariton states with the large dark state reservoir play a decisive role in determining the dynamics of the emission and transient absorption properties of the hybridized light-quantum dot solid system. Our results open the route for the investigation of PQD solids as polaritonic optoelectronic materials. |
| publishDate |
2021 |
| dc.date.none.fl_str_mv |
2021 2024 2024 2024 |
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info:eu-repo/semantics/dataset http://purl.org/coar/resource_type/c_ddb1 |
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dataset |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/343100 https://doi.org/10.20350/digitalCSIC/16079 |
| url |
http://hdl.handle.net/10261/343100 https://doi.org/10.20350/digitalCSIC/16079 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
#PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-116593RB-I00 info:eu-repo/grantAgreement/AEI//TED2021-129679B-C22 info:eu-repo/grantAgreement/EC/H2020/956270 info:eu-repo/grantAgreement/AEI//PID2021-125894NB-I00 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2018-000805-M Bujalance, Clara; Calió, Laura; Dirin, Dmitry N.; Tiede, David O.; Galisteo-López, Juan F.; Feist, Johannes; García-Vidal, Francisco J.; Kovalenko, Maksym V.; Míguez, Hernán. Strong Light-Matter Coupling in Lead Halide Perovskite Quantum Dot Solids. https://doi.org/10.1021/acsnano.3c10358. http://hdl.handle.net/10261/346487 Bujalance, Clara; Calió, Laura; Dirin, Dmitry N.; Tiede, David O.; Galisteo-López, Juan F.; Feist, Johannes; García-Vidal, Francisco J.; Kovalenko, Maksym V.; Míguez, Hernán; 2023; Strong light-matter coupling in lead halide perovskite quantum dot solids [Preprint]; arXiv; https://doi.org/10.48550/arXiv.2306.10884 Sí |
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info:eu-repo/semantics/openAccess |
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openAccess |
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DIGITAL.CSIC |
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DIGITAL.CSIC |
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reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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Strong light-matter coupling in lead halide perovskite quantum dot solids [Dataset]Bujalance, ClaraCalió, LauraDirin, Dmitry N.Tiede, David O.Galisteo-López, Juan F.Feist, JohannesGarcía-Vidal, Francisco J.Kovalenko, Maksym V.Míguez, HernánPolaritonsOptical MicrocavitiesQuantum dot solidsPerovskitesStrong exciton-photon CouplingStrong coupling between lead halide perovskite materials and optical resonators enables both the polaritonic control of the photophysical properties of these emerging semiconductors and the observation of novel fundamental physical phenomena. However, the difficulty to achieve optical-quality perovskite quantum dot (PQD) films showing well-defined excitonic transitions has prevented the study of strong light-matter coupling in these materials, central to the field of optoelectronics. Herein we demonstrate the formation at room temperature of multiple cavity exciton-polaritons in metallic resonators embedding highly transparent Cesium Lead Bromide quantum dot (CsPbBr3-QD) solids, revealed by a significant reconfiguration of the absorption and emission properties of the system. Our results indicate that the effects of biexciton interaction or large polaron formation, frequently invoked to explain the properties of PQDs, are seemingly absent or compensated by other more conspicuous effects in the CsPbBr3-QD optical cavity. We observe that strong coupling enables a significant reduction of the photoemission linewidth, as well as the ultrafast modulation of the optical absorption, controllable by means of the excitation fluence. We find that the interplay of the polariton states with the large dark state reservoir play a decisive role in determining the dynamics of the emission and transient absorption properties of the hybridized light-quantum dot solid system. Our results open the route for the investigation of PQD solids as polaritonic optoelectronic materials.This project has received funding from the Spanish Ministry of Science and Innovation-Agencia Estatal de Investigación (MICIN-AEI) under grants PID2020-116593RB-I00 and TED2021-129679B-C22, funded by MCIN/AEI/ 10.13039/501100011033 and by Unión Europea NextGenerationEU/PRTR, by the Junta de Andalucía under grant P18-RT-2291 (FEDER/UE) and the Innovative Training Network (ITN) Persephone, funded by the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 956270. M. V. K. and D.D.; from the Air Force Office of Scientific Research and the Office of Naval Research (award number FA8655-21-1-7013); from the Spanish MICIN–AEI under grants PID2021-125894NB-I00 and CEX2018-000805-M (through the María de Maeztu program for Units of Excellence in Research and Development); from Junta de Andalucía and the European Regional Development Funds (EU-FEDER) under program (DOC_00220).With funding from the Spanish government through the "Severo Ochoa Centre of Excellence" accreditation (CEX2018-000805-M).Folder List: 1. Figure_1 - Figure1_d: Absorptance; PL (counts) dispersion QDs - Figure1_e: Absorptance; PL (counts) film QDs - Figure1_f: Absorptance cavity QDs 26º, 36º, 46º - Figure1_g: Absorptance; second derivative dispersion QDs - Figure1_h: Absorptance; second derivative film QDs - Figure1_i: Absorptance; second derivative cavity QDs 2. Figure_2 -Figure2_a_experimental_map_right: experimental dispersion A vs. k|| s-polarised -Figure2_a_theoretical_map_left: theoretical dispersion A vs. k|| s-polarised -Figure2_a_experimental_maxima: experimental A maxima s-polarised -Figure2_a_JCmodel: theoretical polaritonic dispersion from JC model s-polarised -Figure2_b_experimental_map_right: experimental dispersion A vs. k|| p-polarised -Figure2_b_theoretical_map_left: theoretical dispersion A vs. k|| p-polarised -Figure2_b_experimental_maxima: experimental A maxima p-polarised -Figure2_b_JCmodel: theoretical polaritonic dispersion from JC model p-polarised -Figure2_c: Hopfield coeffcients lower polariton -Figure2_d: Hopfield coeffcients middle polariton -Figure2_e: Hopfield coeffcients upper polariton 3. Figure_3 -Figure3_a: transient absorption map of the cavity vs. wavelength -Figure3_b: delta A at 0.4 and 10ps vs. wavelength -Figure3_c: |delta A| vs. time -Figure3_d: transient absorptance (delta A + A) of the cavity vs. wavelength -Figure3_e: deconvoluted delta A -Figure3_f: deconvoluted delta A + A -Figure3_g: dinamics of I_PIA, Area_overlap MP-LP, and energy splitting vs. time 4. Figure_4 -Figure4_a: PL of QDs film vs. angle of collection -Figure4_b: Pl of QDs cavity vs. angle of collection -Figure4_c: experimental dispersion A vs. k|| -Figure4_d: PL dispersion vs. k|| -Figure4_e_data: PL decay data vs.time of colloidal dispersion, film and cavity -Figure4_e_fits: lognormal fit of PL decay data vs.time -Figure4_f: distribution of decay ratesPeer reviewedDIGITAL.CSICMinisterio de Ciencia e Innovación (España)Agencia Estatal de Investigación (España)European CommissionJunta de AndalucíaAir Force Office of Scientific Research (US)Office of Naval Research (US)Míguez, Hernán [0000-0003-2925-6360]Míguez, Hernán [h.miguez@csic.es]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2024202420212024info:eu-repo/semantics/datasethttp://purl.org/coar/resource_type/c_ddb1txthttp://hdl.handle.net/10261/343100https://doi.org/10.20350/digitalCSIC/16079reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-116593RB-I00info:eu-repo/grantAgreement/AEI//TED2021-129679B-C22info:eu-repo/grantAgreement/EC/H2020/956270info:eu-repo/grantAgreement/AEI//PID2021-125894NB-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2018-000805-MBujalance, Clara; Calió, Laura; Dirin, Dmitry N.; Tiede, David O.; Galisteo-López, Juan F.; Feist, Johannes; García-Vidal, Francisco J.; Kovalenko, Maksym V.; Míguez, Hernán. Strong Light-Matter Coupling in Lead Halide Perovskite Quantum Dot Solids. https://doi.org/10.1021/acsnano.3c10358. http://hdl.handle.net/10261/346487Bujalance, Clara; Calió, Laura; Dirin, Dmitry N.; Tiede, David O.; Galisteo-López, Juan F.; Feist, Johannes; García-Vidal, Francisco J.; Kovalenko, Maksym V.; Míguez, Hernán; 2023; Strong light-matter coupling in lead halide perovskite quantum dot solids [Preprint]; arXiv; https://doi.org/10.48550/arXiv.2306.10884Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3431002026-05-22T06:33:51Z |
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15,81155 |