Exciton-Polaritons in Nanoscale Metal-Organic Frameworks: A Platform for the Reversible Modulation of Strong Light-Matter Coupling via the Chemical Environment [Dataset]
We demonstrate robust exciton–polariton formation in planar metallic optical cavities using porphyrin-based MOF nanoparticles. The designed structure enables strong light–matter coupling (Rabi splitting up to 440 meV) through precise thickness control and alignment of excitonic dipoles with the cavi...
| Autores: | , , , , , , , |
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| Tipo de recurso: | conjunto de datos |
| Fecha de publicación: | 2026 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/423822 |
| Acceso en línea: | http://hdl.handle.net/10261/423822 |
| Access Level: | acceso abierto |
| Palabra clave: | Metal-organic frameworks Strong light-matter coupling Exciton-polaritons Optical microcavities |
| Sumario: | We demonstrate robust exciton–polariton formation in planar metallic optical cavities using porphyrin-based MOF nanoparticles. The designed structure enables strong light–matter coupling (Rabi splitting up to 440 meV) through precise thickness control and alignment of excitonic dipoles with the cavity field. The system also shows reversible tuning of the polariton splitting with vapor pressure changes, due to adsorption in the MOF pores and the solvatochromic nature of the porphyrin ligands. |
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