Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli

2-C-Methyl-d-erythritol cyclodiphosphate is converted into (E)-4-hydroxy-3-methylbut-2-enyl diphosphate by a cell-free system from an Escherichia coli strain overexpressing the gcpE gene. The latter diphosphate, representing probably the last intermediate in the MEP pathway for isoprenoid biosynthes...

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Detalles Bibliográficos
Autores: Wolff, Murielle, Seemann, Myriam, Grosdemange Billiard, Catherine, Tritsch, Denis, Campos Martínez, Narciso, Rodríguez Concepción, Manuel, Boronat i Margosa, Albert, Rohmer, Michel
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2002
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/225957
Acceso en línea:https://hdl.handle.net/2445/225957
Access Level:acceso abierto
Palabra clave:Química bioinorgànica
Escheríchia coli
Bioinorganic chemistry
Escherichia coli
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spelling Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coliWolff, MurielleSeemann, MyriamGrosdemange Billiard, CatherineTritsch, DenisCampos Martínez, NarcisoRodríguez Concepción, ManuelBoronat i Margosa, AlbertRohmer, MichelQuímica bioinorgànicaEscheríchia coliBioinorganic chemistryEscherichia coli2-C-Methyl-d-erythritol cyclodiphosphate is converted into (E)-4-hydroxy-3-methylbut-2-enyl diphosphate by a cell-free system from an Escherichia coli strain overexpressing the gcpE gene. The latter diphosphate, representing probably the last intermediate in the MEP pathway for isoprenoid biosynthesis, was identified by comparison with reference material obtained by chemical synthesis.Elsevier Ltd.2026202620022026info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersion5 p.application/pdfhttps://hdl.handle.net/2445/225957Articles publicats en revistes (Bioquímica i Biomedicina Molecular)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésVersió postprint del document publicat a: https://doi.org/10.1016/S0040-4039(02)00293-9Tetrahedron Letters, 2002, vol. 43, num.14, p. 2555-2559https://doi.org/10.1016/S0040-4039(02)00293-9(c) Elsevier Ltd., 2002info:eu-repo/semantics/openAccessoai:recercat.cat:2445/2259572026-05-29T05:05:01Z
dc.title.none.fl_str_mv Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli
title Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli
spellingShingle Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli
Wolff, Murielle
Química bioinorgànica
Escheríchia coli
Bioinorganic chemistry
Escherichia coli
title_short Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli
title_full Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli
title_fullStr Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli
title_full_unstemmed Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli
title_sort Isoprenoid biosynthesis via the methylerythritol phosphate pathway. (E)-4-Hydroxy-3-methylbut-2-enyl diphosphate: chemical synthesis and formation from methylerythritol cyclodiphosphate by a cell-free system from Escherichia coli
dc.creator.none.fl_str_mv Wolff, Murielle
Seemann, Myriam
Grosdemange Billiard, Catherine
Tritsch, Denis
Campos Martínez, Narciso
Rodríguez Concepción, Manuel
Boronat i Margosa, Albert
Rohmer, Michel
author Wolff, Murielle
author_facet Wolff, Murielle
Seemann, Myriam
Grosdemange Billiard, Catherine
Tritsch, Denis
Campos Martínez, Narciso
Rodríguez Concepción, Manuel
Boronat i Margosa, Albert
Rohmer, Michel
author_role author
author2 Seemann, Myriam
Grosdemange Billiard, Catherine
Tritsch, Denis
Campos Martínez, Narciso
Rodríguez Concepción, Manuel
Boronat i Margosa, Albert
Rohmer, Michel
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Química bioinorgànica
Escheríchia coli
Bioinorganic chemistry
Escherichia coli
topic Química bioinorgànica
Escheríchia coli
Bioinorganic chemistry
Escherichia coli
description 2-C-Methyl-d-erythritol cyclodiphosphate is converted into (E)-4-hydroxy-3-methylbut-2-enyl diphosphate by a cell-free system from an Escherichia coli strain overexpressing the gcpE gene. The latter diphosphate, representing probably the last intermediate in the MEP pathway for isoprenoid biosynthesis, was identified by comparison with reference material obtained by chemical synthesis.
publishDate 2002
dc.date.none.fl_str_mv 2002
2026
2026
2026
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/225957
url https://hdl.handle.net/2445/225957
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1016/S0040-4039(02)00293-9
Tetrahedron Letters, 2002, vol. 43, num.14, p. 2555-2559
https://doi.org/10.1016/S0040-4039(02)00293-9
dc.rights.none.fl_str_mv (c) Elsevier Ltd., 2002
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) Elsevier Ltd., 2002
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 5 p.
application/pdf
dc.publisher.none.fl_str_mv Elsevier Ltd.
publisher.none.fl_str_mv Elsevier Ltd.
dc.source.none.fl_str_mv Articles publicats en revistes (Bioquímica i Biomedicina Molecular)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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