Characterization and classification of Spanish paprika (Capsicum annuum L.) by liquid chromatography coupled to electrochemical detection with screen-printed carbon-based nanomaterials electrodes

Screen-printed electrodes based on graphite, carbon nanotubes, carbon nanofibers, and graphene were tested as amperometric detectors for the determination of polyphenols by high performance liquid chromatography (HPLC). The chromatographic performance as well as the obtained sensitivity, detection a...

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Bibliographic Details
Authors: Serrano i Plana, Núria, Cetó Alseda, Xavier, Núñez Burcio, Oscar, Aragó, Miriam, Gámez, Alejandro, Ariño Blasco, Cristina, Díaz Cruz, José Manuel
Format: article
Status:Versión aceptada para publicación
Publication Date:2018
Country:España
Institution:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repository:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/123823
Online Access:https://hdl.handle.net/2445/123823
Access Level:Open access
Keyword:Cromatografia de líquids
Electroquímica
Polifenols
Pebrots
Liquid chromatography
Electrochemistry
Polyphenols
Peppers
Description
Summary:Screen-printed electrodes based on graphite, carbon nanotubes, carbon nanofibers, and graphene were tested as amperometric detectors for the determination of polyphenols by high performance liquid chromatography (HPLC). The chromatographic performance as well as the obtained sensitivity, detection and quantification limits suggest that carbon nanofibers modified screen-printed electrode (SPCE-CNF) is the amperometric sensor that provides the best analytical performance. Upon this confirmation, chromatographic data obtained using SPCE-CNF were exploited by means of linear discriminant analysis to successfully characterize and classify 96 Spanish paprika (Capsicum annuum L.) samples with protected designation of origin: from La Vera (including sweet, bittersweet and spicy types) and from Murcia (including sweet and spicy types).