Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound

A great deal of interest has focused on the role of metal ions as the active centers in the fixation of CO2 and its transformation. Activation of CO2 by hydroxo and oxo metal complexes to afford metal hydrogencarbonato and carbonato species, respectively, is related to the function of the carbonic a...

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Autores: Santamaría, David, Cano Sierra, Jesús|||0000-0002-6643-7534, Royo Gracia, Pascual, González Mosquera, Marta Elena|||0000-0003-2248-3050, Cuenca Agreda, José Tomás|||0000-0001-5830-5833, Frutos Gaite, Luis Manuel|||0000-0003-1036-7108
Tipo de recurso: artículo
Fecha de publicación:2005
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/4197
Acceso en línea:http://hdl.handle.net/10017/4197
https://dx.doi.org/10.1002/ange.200500716
Access Level:acceso abierto
Palabra clave:Silicon
Titanium
Ab initio calculations
Carbon dioxide fixation
Ciencia
Química inorgánica
Science
Chemistry, inorganic
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spelling Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compoundSantamaría, DavidCano Sierra, Jesús|||0000-0002-6643-7534Royo Gracia, PascualGonzález Mosquera, Marta Elena|||0000-0003-2248-3050Cuenca Agreda, José Tomás|||0000-0001-5830-5833Frutos Gaite, Luis Manuel|||0000-0003-1036-7108SiliconTitaniumAb initio calculationsCarbon dioxide fixationCienciaQuímica inorgánicaScienceChemistry, inorganicA great deal of interest has focused on the role of metal ions as the active centers in the fixation of CO2 and its transformation. Activation of CO2 by hydroxo and oxo metal complexes to afford metal hydrogencarbonato and carbonato species, respectively, is related to the function of the carbonic anhydrase metalloenzyme, which catalyzes the physiologically important hydration of CO2 to hydrogencarbonate.Comisión Asesora de Investigación Científica y TécnicaJohn Wiley & Sons20052005-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/4197https://dx.doi.org/10.1002/ange.200500716reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengCAICYT Not available MAT2004-02614 Diseño, síntesis y caracterización de catalizadores para producir nuevos materiales poliolefínicosCAICTY Not available BQU2003-07281 Propiedades estructurales, espectroscópica y procesos fotoquímicos y de transferencia de energía en compuestos de interés en química orgánica y biorgánicaopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/41972026-06-18T11:13:07Z
dc.title.none.fl_str_mv Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
title Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
spellingShingle Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
Santamaría, David
Silicon
Titanium
Ab initio calculations
Carbon dioxide fixation
Ciencia
Química inorgánica
Science
Chemistry, inorganic
title_short Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
title_full Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
title_fullStr Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
title_full_unstemmed Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
title_sort Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
dc.creator.none.fl_str_mv Santamaría, David
Cano Sierra, Jesús|||0000-0002-6643-7534
Royo Gracia, Pascual
González Mosquera, Marta Elena|||0000-0003-2248-3050
Cuenca Agreda, José Tomás|||0000-0001-5830-5833
Frutos Gaite, Luis Manuel|||0000-0003-1036-7108
author Santamaría, David
author_facet Santamaría, David
Cano Sierra, Jesús|||0000-0002-6643-7534
Royo Gracia, Pascual
González Mosquera, Marta Elena|||0000-0003-2248-3050
Cuenca Agreda, José Tomás|||0000-0001-5830-5833
Frutos Gaite, Luis Manuel|||0000-0003-1036-7108
author_role author
author2 Cano Sierra, Jesús|||0000-0002-6643-7534
Royo Gracia, Pascual
González Mosquera, Marta Elena|||0000-0003-2248-3050
Cuenca Agreda, José Tomás|||0000-0001-5830-5833
Frutos Gaite, Luis Manuel|||0000-0003-1036-7108
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Silicon
Titanium
Ab initio calculations
Carbon dioxide fixation
Ciencia
Química inorgánica
Science
Chemistry, inorganic
topic Silicon
Titanium
Ab initio calculations
Carbon dioxide fixation
Ciencia
Química inorgánica
Science
Chemistry, inorganic
description A great deal of interest has focused on the role of metal ions as the active centers in the fixation of CO2 and its transformation. Activation of CO2 by hydroxo and oxo metal complexes to afford metal hydrogencarbonato and carbonato species, respectively, is related to the function of the carbonic anhydrase metalloenzyme, which catalyzes the physiologically important hydration of CO2 to hydrogencarbonate.
publishDate 2005
dc.date.none.fl_str_mv 2005
2005-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/4197
https://dx.doi.org/10.1002/ange.200500716
url http://hdl.handle.net/10017/4197
https://dx.doi.org/10.1002/ange.200500716
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv CAICYT Not available MAT2004-02614 Diseño, síntesis y caracterización de catalizadores para producir nuevos materiales poliolefínicos
CAICTY Not available BQU2003-07281 Propiedades estructurales, espectroscópica y procesos fotoquímicos y de transferencia de energía en compuestos de interés en química orgánica y biorgánica
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300719

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