Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound
A great deal of interest has focused on the role of metal ions as the active centers in the fixation of CO2 and its transformation. Activation of CO2 by hydroxo and oxo metal complexes to afford metal hydrogencarbonato and carbonato species, respectively, is related to the function of the carbonic a...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2005 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4197 |
| Acceso en línea: | http://hdl.handle.net/10017/4197 https://dx.doi.org/10.1002/ange.200500716 |
| Access Level: | acceso abierto |
| Palabra clave: | Silicon Titanium Ab initio calculations Carbon dioxide fixation Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | A great deal of interest has focused on the role of metal ions as the active centers in the fixation of CO2 and its transformation. Activation of CO2 by hydroxo and oxo metal complexes to afford metal hydrogencarbonato and carbonato species, respectively, is related to the function of the carbonic anhydrase metalloenzyme, which catalyzes the physiologically important hydration of CO2 to hydrogencarbonate. |
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