A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest

A biphenyl-spaced bis-pyrazolylpyridine ligand interacts with ferrous ions to engender a dimetallic helical coordination cage that encapsulates an Fe3+ tris-anilate complex. The host–guest interaction breaks the symmetry of the Fe2+ centers causing a differential spin crossover behavior in them that...

Descripción completa

Detalles Bibliográficos
Autores: Barrios Moreno, Leoní Alejandra, Teat, Simon J., Roubeau, Olivier, Aromí Bedmar, Guillem
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/217014
Acceso en línea:https://hdl.handle.net/2445/217014
Access Level:acceso abierto
Palabra clave:Òxids
Ferro
Química supramolecular
Oxides
Iron
Supramolecular chemistry
id ES_265f8aeef7266a77dab3f6fa34baf7ee
oai_identifier_str oai:recercat.cat:2445/217014
network_acronym_str ES
network_name_str España
repository_id_str
spelling A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guestBarrios Moreno, Leoní AlejandraTeat, Simon J.Roubeau, OlivierAromí Bedmar, GuillemÒxidsFerroQuímica supramolecularOxidesIronSupramolecular chemistryA biphenyl-spaced bis-pyrazolylpyridine ligand interacts with ferrous ions to engender a dimetallic helical coordination cage that encapsulates an Fe3+ tris-anilate complex. The host–guest interaction breaks the symmetry of the Fe2+ centers causing a differential spin crossover behavior in them that can be followed in great detail crystallographically.Royal Society of Chemistry2024202420232024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion4 p.application/pdfhttps://hdl.handle.net/2445/217014Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésReproducció del document publicat a: https://doi.org/10.1039/d3cc02278aChemical Communications, 2023, vol. 59, p. 10628-10631https://doi.org/10.1039/d3cc02278acc-by (c) L. A. Barrios et al., 2023http://creativecommons.org/licenses/by/3.0/es/info:eu-repo/semantics/openAccessoai:recercat.cat:2445/2170142026-05-29T05:05:01Z
dc.title.none.fl_str_mv A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
title A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
spellingShingle A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
Barrios Moreno, Leoní Alejandra
Òxids
Ferro
Química supramolecular
Oxides
Iron
Supramolecular chemistry
title_short A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
title_full A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
title_fullStr A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
title_full_unstemmed A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
title_sort A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest
dc.creator.none.fl_str_mv Barrios Moreno, Leoní Alejandra
Teat, Simon J.
Roubeau, Olivier
Aromí Bedmar, Guillem
author Barrios Moreno, Leoní Alejandra
author_facet Barrios Moreno, Leoní Alejandra
Teat, Simon J.
Roubeau, Olivier
Aromí Bedmar, Guillem
author_role author
author2 Teat, Simon J.
Roubeau, Olivier
Aromí Bedmar, Guillem
author2_role author
author
author
dc.subject.none.fl_str_mv Òxids
Ferro
Química supramolecular
Oxides
Iron
Supramolecular chemistry
topic Òxids
Ferro
Química supramolecular
Oxides
Iron
Supramolecular chemistry
description A biphenyl-spaced bis-pyrazolylpyridine ligand interacts with ferrous ions to engender a dimetallic helical coordination cage that encapsulates an Fe3+ tris-anilate complex. The host–guest interaction breaks the symmetry of the Fe2+ centers causing a differential spin crossover behavior in them that can be followed in great detail crystallographically.
publishDate 2023
dc.date.none.fl_str_mv 2023
2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/217014
url https://hdl.handle.net/2445/217014
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1039/d3cc02278a
Chemical Communications, 2023, vol. 59, p. 10628-10631
https://doi.org/10.1039/d3cc02278a
dc.rights.none.fl_str_mv cc-by (c) L. A. Barrios et al., 2023
http://creativecommons.org/licenses/by/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by (c) L. A. Barrios et al., 2023
http://creativecommons.org/licenses/by/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 4 p.
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869404817989828608
score 15,812429

Similares en LA Referencia