A ferric guest inside a spin crossover ferrous helicate
A designed dimetallic Fe(II) helicate made with biphenylenebridged bispyrazolylpyridine ligands and exhibiting a process of spin crossover at temperatures above ambient is shown to encapsulate an S = 5/2 tris-oxalato Fe(III) ion. The spin relaxation dynamics of this guest are strongly reduced upon e...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/195691 |
| Acceso en línea: | https://hdl.handle.net/2445/195691 |
| Access Level: | acceso abierto |
| Palabra clave: | Lligands Ferro Química supramolecular Ligands Iron Supramolecular chemistry |
| Sumario: | A designed dimetallic Fe(II) helicate made with biphenylenebridged bispyrazolylpyridine ligands and exhibiting a process of spin crossover at temperatures above ambient is shown to encapsulate an S = 5/2 tris-oxalato Fe(III) ion. The spin relaxation dynamics of this guest are strongly reduced upon encapsulation |
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