Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)

In each of the two independent molecules in the asymmetric unit of the title compound, [CdI2(C18H14N4O)], the N,O,N'-tridentate N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I2NO pentacoordination sphere, with a distorted square...

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Detalles Bibliográficos
Autores: Atioglu, Zeliha, Akbari Afkhami, Farhad, Akkurt, Mehmet, Akbar Khandar, Ali, Choquesillo-Lazarte, Duane
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/204908
Acceso en línea:http://hdl.handle.net/10261/204908
Access Level:acceso abierto
Palabra clave:Crystal structures
Cadmium
Iodide
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repository_id_str
spelling Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)Atioglu, ZelihaAkbari Afkhami, FarhadAkkurt, MehmetAkbar Khandar, AliChoquesillo-Lazarte, DuaneCrystal structuresCadmiumIodideIn each of the two independent molecules in the asymmetric unit of the title compound, [CdI2(C18H14N4O)], the N,O,N'-tridentate N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I2NO pentacoordination sphere, with a distorted square-pyramidal geometry, with an I atom in the apical position. Both molecules feature an intramolecular N - H⋯N hydrogen bond. In the crystal, weak aromatic π-π stacking interactions [centroid-centroid separation = 3.830 (2) Å] link the molecules into dimers.FAA and AAK thank the University of Tabriz for the financial support of this research.International Union of CrystallographyUniversity of TabrizConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2020202020192020info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/204908reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1107/S2056989019008831Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2049082026-05-22T06:33:51Z
dc.title.none.fl_str_mv Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)
title Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)
spellingShingle Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)
Atioglu, Zeliha
Crystal structures
Cadmium
Iodide
title_short Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)
title_full Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)
title_fullStr Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)
title_sort Crystal structure and Hirshfeld surface analysis of diiodido{N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ2 N',O}cadmium(II)
dc.creator.none.fl_str_mv Atioglu, Zeliha
Akbari Afkhami, Farhad
Akkurt, Mehmet
Akbar Khandar, Ali
Choquesillo-Lazarte, Duane
author Atioglu, Zeliha
author_facet Atioglu, Zeliha
Akbari Afkhami, Farhad
Akkurt, Mehmet
Akbar Khandar, Ali
Choquesillo-Lazarte, Duane
author_role author
author2 Akbari Afkhami, Farhad
Akkurt, Mehmet
Akbar Khandar, Ali
Choquesillo-Lazarte, Duane
author2_role author
author
author
author
dc.contributor.none.fl_str_mv University of Tabriz
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Crystal structures
Cadmium
Iodide
topic Crystal structures
Cadmium
Iodide
description In each of the two independent molecules in the asymmetric unit of the title compound, [CdI2(C18H14N4O)], the N,O,N'-tridentate N'-[(E)-(phenyl)(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide ligand and two iodide anions form an I2NO pentacoordination sphere, with a distorted square-pyramidal geometry, with an I atom in the apical position. Both molecules feature an intramolecular N - H⋯N hydrogen bond. In the crystal, weak aromatic π-π stacking interactions [centroid-centroid separation = 3.830 (2) Å] link the molecules into dimers.
publishDate 2019
dc.date.none.fl_str_mv 2019
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/204908
url http://hdl.handle.net/10261/204908
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv http://dx.doi.org/10.1107/S2056989019008831
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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