Midgap traps related to compensation processes in CdTe alloys

We study, by cathodoluminescence and junction spectroscopy methods, the deep traps located near midgap in semiconducting and semi-insulating II-VI compounds, namely, undoped CdTe, CdTe:Cl, and Cd0.8Zn0.2Te. In order to understand the role such deep levels play in the control of the electrical proper...

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Detalles Bibliográficos
Autores: Castaldini, A., Cavallini, A., Fraboni, B., Fernández Sánchez, Paloma, Piqueras De Noriega, Francisco Javier
Tipo de recurso: artículo
Fecha de publicación:1997
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/59148
Acceso en línea:https://hdl.handle.net/20.500.14352/59148
Access Level:acceso abierto
Palabra clave:538.9
Current Transient Spectroscopy
Deep Centers
Defects
Detectors
Crystals
Cathodoluminescence
Cd1-Xznxte
Física de materiales
Descripción
Sumario:We study, by cathodoluminescence and junction spectroscopy methods, the deep traps located near midgap in semiconducting and semi-insulating II-VI compounds, namely, undoped CdTe, CdTe:Cl, and Cd0.8Zn0.2Te. In order to understand the role such deep levels play in the control of the electrical properties of the material, it appears necessary to determine their character, donor, or acceptor, in addition to their activation energy and capture cross section. Photoinduced-current transient spectroscopy and photo deep-level transient spectroscopy are used to investigate the semi-insulating (SI) samples, and a comparison of the complementary results obtained allows us to identify an acceptor trap, labeled H, and an electron trap, labeled E. Level H is common to all investigated compounds, while E is present only in CdTe:Cl samples. This provides clear experimental evidence of the presence of a deep trap in CdTe:Cl, which could be a good candidate for the deep donor level needed to explain the compensation process of SI CdTe:Cl.