Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds

(C6Cl5)3Sb and (C6Cl5)3Bi have been isolated from SbCl3 or BiCl3 and C6Cl5Li. AsCl3 gives only (C6Cl5)2AsCl even with a large excess of C6Cl5Li. Treatment of (C6Cl5)3Sb with halogens gives (C6Cl5)3SbX2 (X=Cl, Br). Br2 does not react with (C6Cl5)2AsCl whereas Cl2 gives an intractable residue which is...

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Detalles Bibliográficos
Autores: Otero Montero, Antonio, Royo Gracia, Pascual
Tipo de recurso: artículo
Fecha de publicación:1979
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/4816
Acceso en línea:http://hdl.handle.net/10017/4816
https://dx.doi.org/10.1016/S0022-328X(00)82656-X
Access Level:acceso abierto
Palabra clave:Arsenic
Antimony
Bismuth
Ciencia
Química inorgánica
Science
Chemistry, inorganic
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spelling Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compoundsOtero Montero, AntonioRoyo Gracia, PascualArsenicAntimonyBismuthCienciaQuímica inorgánicaScienceChemistry, inorganic(C6Cl5)3Sb and (C6Cl5)3Bi have been isolated from SbCl3 or BiCl3 and C6Cl5Li. AsCl3 gives only (C6Cl5)2AsCl even with a large excess of C6Cl5Li. Treatment of (C6Cl5)3Sb with halogens gives (C6Cl5)3SbX2 (X=Cl, Br). Br2 does not react with (C6Cl5)2AsCl whereas Cl2 gives an intractable residue which is rapidly hydrolysed to [(C6Cl5)2As]2O. Treatment of (C6Cl5)3Bi with halogens cleaves the C-Bi bonds to give C6Cl5X and unidentified oxohalobismuth(III) derivatives.Elsevier19791979-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/4816https://dx.doi.org/10.1016/S0022-328X(00)82656-Xreponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/48162026-06-18T11:13:07Z
dc.title.none.fl_str_mv Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
title Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
spellingShingle Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
Otero Montero, Antonio
Arsenic
Antimony
Bismuth
Ciencia
Química inorgánica
Science
Chemistry, inorganic
title_short Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
title_full Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
title_fullStr Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
title_full_unstemmed Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
title_sort Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
dc.creator.none.fl_str_mv Otero Montero, Antonio
Royo Gracia, Pascual
author Otero Montero, Antonio
author_facet Otero Montero, Antonio
Royo Gracia, Pascual
author_role author
author2 Royo Gracia, Pascual
author2_role author
dc.subject.none.fl_str_mv Arsenic
Antimony
Bismuth
Ciencia
Química inorgánica
Science
Chemistry, inorganic
topic Arsenic
Antimony
Bismuth
Ciencia
Química inorgánica
Science
Chemistry, inorganic
description (C6Cl5)3Sb and (C6Cl5)3Bi have been isolated from SbCl3 or BiCl3 and C6Cl5Li. AsCl3 gives only (C6Cl5)2AsCl even with a large excess of C6Cl5Li. Treatment of (C6Cl5)3Sb with halogens gives (C6Cl5)3SbX2 (X=Cl, Br). Br2 does not react with (C6Cl5)2AsCl whereas Cl2 gives an intractable residue which is rapidly hydrolysed to [(C6Cl5)2As]2O. Treatment of (C6Cl5)3Bi with halogens cleaves the C-Bi bonds to give C6Cl5X and unidentified oxohalobismuth(III) derivatives.
publishDate 1979
dc.date.none.fl_str_mv 1979
1979-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/4816
https://dx.doi.org/10.1016/S0022-328X(00)82656-X
url http://hdl.handle.net/10017/4816
https://dx.doi.org/10.1016/S0022-328X(00)82656-X
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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