Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
(C6Cl5)3Sb and (C6Cl5)3Bi have been isolated from SbCl3 or BiCl3 and C6Cl5Li. AsCl3 gives only (C6Cl5)2AsCl even with a large excess of C6Cl5Li. Treatment of (C6Cl5)3Sb with halogens gives (C6Cl5)3SbX2 (X=Cl, Br). Br2 does not react with (C6Cl5)2AsCl whereas Cl2 gives an intractable residue which is...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1979 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4816 |
| Acceso en línea: | http://hdl.handle.net/10017/4816 https://dx.doi.org/10.1016/S0022-328X(00)82656-X |
| Access Level: | acceso abierto |
| Palabra clave: | Arsenic Antimony Bismuth Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | (C6Cl5)3Sb and (C6Cl5)3Bi have been isolated from SbCl3 or BiCl3 and C6Cl5Li. AsCl3 gives only (C6Cl5)2AsCl even with a large excess of C6Cl5Li. Treatment of (C6Cl5)3Sb with halogens gives (C6Cl5)3SbX2 (X=Cl, Br). Br2 does not react with (C6Cl5)2AsCl whereas Cl2 gives an intractable residue which is rapidly hydrolysed to [(C6Cl5)2As]2O. Treatment of (C6Cl5)3Bi with halogens cleaves the C-Bi bonds to give C6Cl5X and unidentified oxohalobismuth(III) derivatives. |
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