Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors

The preparation of nanostructured hierarchical MnNiCoO metal oxides as efficient supercapacitors of different structures and configurations especially for the miniaturized electronics is still a challenge. In this context, we report template free facile hydrothermal synthesis of hierarchical nanostr...

Full description

Bibliographic Details
Authors: Tamboli, Mohaseen S.|||0000-0003-1749-2681, Dubal, Deepak P.|||0000-0002-2337-676X, Patil, Santosh S., Shaikh, Asiya F., Deonikar, Virendrakumar G.|||0000-0001-6603-8333, Kulkarni, Milind V., Maldar, Noormahamad N., Gómez-Romero, Pedro|||0000-0002-6208-5340, Kale, Bharat B.|||0000-0003-0556-9477, Patil, Deepak R.
Format: article
Publication Date:2017
Country:España
Institution:Universitat Autònoma de Barcelona
Repository:Dipòsit Digital de Documents de la UAB
Language:English
OAI Identifier:oai:ddd.uab.cat:225314
Online Access:https://ddd.uab.cat/record/225314
https://dx.doi.org/urn:doi:10.1016/j.cej.2016.08.086
Access Level:Open access
Keyword:Mixed transition metal oxides
Nanostructures
Asymmetric capacitor
id ES_253efce9ffff4ed1eecdfa732beb4d90
oai_identifier_str oai:ddd.uab.cat:225314
network_acronym_str ES
network_name_str España
repository_id_str
spelling Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitorsTamboli, Mohaseen S.|||0000-0003-1749-2681Dubal, Deepak P.|||0000-0002-2337-676XPatil, Santosh S.Shaikh, Asiya F.Deonikar, Virendrakumar G.|||0000-0001-6603-8333Kulkarni, Milind V.Maldar, Noormahamad N.Gómez-Romero, Pedro|||0000-0002-6208-5340Kale, Bharat B.|||0000-0003-0556-9477Patil, Deepak R.Mixed transition metal oxidesNanostructuresAsymmetric capacitorThe preparation of nanostructured hierarchical MnNiCoO metal oxides as efficient supercapacitors of different structures and configurations especially for the miniaturized electronics is still a challenge. In this context, we report template free facile hydrothermal synthesis of hierarchical nanostructured MnNiCoO with excellent supercapacitive performance. Significantly, the morphology of pure MnCoO transformed from 3D microcubes to 1D nanowires with incorporation of Ni. The electrochemical study shows highest specific capacitance i.e. 1762 F/g for MnNiCoO with high cycling stability of 89.2% which is much higher than pristine MnCoO and NiCoO. Later, asymmetric capacitor has been fabricated successfully using MnNiCoO nanowires as positive electrode and activated carbon (AC) as negative electrode in a KOH aqueous electrolyte. An asymmetric cell could be cycled reversibly in the high-voltage range of 0-1.5 V and displays intriguing performances with a specific capacitance of 112.8 F/g (6.87 F/cm) and high energy density of 35.2 Wh/kg (2.1 mWh/cm). Importantly, this asymmetric capacitor device exhibits an excellent long cycle life along with 83.2% specific capacitance retained after 2000 cycles. 22017-01-0120172017-01-01Articlehttp://purl.org/coar/resource_type/c_6501SMURhttp://purl.org/coar/version/c_71e4c1898caa6e32info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/225314https://dx.doi.org/urn:doi:10.1016/j.cej.2016.08.086reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2014/SGR-1505open accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, i la comunicació pública de l'obra, sempre que no sigui amb finalitats comercials, i sempre que es reconegui l'autoria de l'obra original. No es permet la creació d'obres derivades.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2253142026-06-06T12:50:31Z
dc.title.none.fl_str_mv Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
title Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
spellingShingle Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
Tamboli, Mohaseen S.|||0000-0003-1749-2681
Mixed transition metal oxides
Nanostructures
Asymmetric capacitor
title_short Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
title_full Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
title_fullStr Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
title_full_unstemmed Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
title_sort Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
dc.creator.none.fl_str_mv Tamboli, Mohaseen S.|||0000-0003-1749-2681
Dubal, Deepak P.|||0000-0002-2337-676X
Patil, Santosh S.
Shaikh, Asiya F.
Deonikar, Virendrakumar G.|||0000-0001-6603-8333
Kulkarni, Milind V.
Maldar, Noormahamad N.
Gómez-Romero, Pedro|||0000-0002-6208-5340
Kale, Bharat B.|||0000-0003-0556-9477
Patil, Deepak R.
author Tamboli, Mohaseen S.|||0000-0003-1749-2681
author_facet Tamboli, Mohaseen S.|||0000-0003-1749-2681
Dubal, Deepak P.|||0000-0002-2337-676X
Patil, Santosh S.
Shaikh, Asiya F.
Deonikar, Virendrakumar G.|||0000-0001-6603-8333
Kulkarni, Milind V.
Maldar, Noormahamad N.
Gómez-Romero, Pedro|||0000-0002-6208-5340
Kale, Bharat B.|||0000-0003-0556-9477
Patil, Deepak R.
author_role author
author2 Dubal, Deepak P.|||0000-0002-2337-676X
Patil, Santosh S.
Shaikh, Asiya F.
Deonikar, Virendrakumar G.|||0000-0001-6603-8333
Kulkarni, Milind V.
Maldar, Noormahamad N.
Gómez-Romero, Pedro|||0000-0002-6208-5340
Kale, Bharat B.|||0000-0003-0556-9477
Patil, Deepak R.
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Mixed transition metal oxides
Nanostructures
Asymmetric capacitor
topic Mixed transition metal oxides
Nanostructures
Asymmetric capacitor
description The preparation of nanostructured hierarchical MnNiCoO metal oxides as efficient supercapacitors of different structures and configurations especially for the miniaturized electronics is still a challenge. In this context, we report template free facile hydrothermal synthesis of hierarchical nanostructured MnNiCoO with excellent supercapacitive performance. Significantly, the morphology of pure MnCoO transformed from 3D microcubes to 1D nanowires with incorporation of Ni. The electrochemical study shows highest specific capacitance i.e. 1762 F/g for MnNiCoO with high cycling stability of 89.2% which is much higher than pristine MnCoO and NiCoO. Later, asymmetric capacitor has been fabricated successfully using MnNiCoO nanowires as positive electrode and activated carbon (AC) as negative electrode in a KOH aqueous electrolyte. An asymmetric cell could be cycled reversibly in the high-voltage range of 0-1.5 V and displays intriguing performances with a specific capacitance of 112.8 F/g (6.87 F/cm) and high energy density of 35.2 Wh/kg (2.1 mWh/cm). Importantly, this asymmetric capacitor device exhibits an excellent long cycle life along with 83.2% specific capacitance retained after 2000 cycles.
publishDate 2017
dc.date.none.fl_str_mv 2
2017-01-01
2017
2017-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
SMUR
http://purl.org/coar/version/c_71e4c1898caa6e32
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/225314
https://dx.doi.org/urn:doi:10.1016/j.cej.2016.08.086
url https://ddd.uab.cat/record/225314
https://dx.doi.org/urn:doi:10.1016/j.cej.2016.08.086
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2014/SGR-1505
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869404745816342528
score 15,300724

Similar Items