General hybrid asymmetric capacitor model: Validation with a commercial lithium ion capacitor

Modelling and numerical simulations play a vital role in the design and optimization of electrochemical energy storage devices. In this study, a general physics-based model is developed to describe Hybrid Asymmetric Capacitors (HACs). A one-dimensional cell is constructed with one faradaic electrode...

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Detalles Bibliográficos
Autores: Campillo Robles, José Miguel, Artetxe, Xabier, Del Teso Sánchez, Karmele, Gutiérrez, César, Macicior, Haritz, Stephan, Röser, Wagner, Ralf, Winter, Martin
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/71462
Acceso en línea:http://hdl.handle.net/10810/71462
Access Level:acceso abierto
Palabra clave:energy storage
hybrid asymmetric capacitor
lithium ion capacitor
theoretical simulations
electrochemical model
finite element model
Descripción
Sumario:Modelling and numerical simulations play a vital role in the design and optimization of electrochemical energy storage devices. In this study, a general physics-based model is developed to describe Hybrid Asymmetric Capacitors (HACs). A one-dimensional cell is constructed with one faradaic electrode, a separator and a capacitive electrode. The model is validated using a commercial Lithium Ion Capacitor (LIC). Galvanostatic charge and discharge processes are simulated with a maximum mean relative error of 7.8%. This suggest that this simple Ohmic model captures the key electrochemical phenomena occurring inside the LIC cell.