OCV Estimation in electrochemical batteries with an unknown linear model and finite excitation
This study introduces a novel observer architecture for estimating the model parameters and the Open Circuit Voltage (from which State of Charge can be obtained) in electrochemical systems that can be modeled through an equivalent circuit, like lithium-ion and vanadium redox-flow batteries. The prop...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2025 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/400641 |
| Acceso en línea: | http://hdl.handle.net/10261/400641 https://api.elsevier.com/content/abstract/scopus_id/105011394149 |
| Access Level: | acceso abierto |
| Palabra clave: | Lithium-ion batteries Parameter identification Relaxation of the persistence of excitation condition SoC estimation Vanadium redox-flow batteries |
| Sumario: | This study introduces a novel observer architecture for estimating the model parameters and the Open Circuit Voltage (from which State of Charge can be obtained) in electrochemical systems that can be modeled through an equivalent circuit, like lithium-ion and vanadium redox-flow batteries. The proposed methodology leverages the recently proposed Generalized Parameter Estimation Based Observer framework to transform the state estimation problem into a parameter estimation problem. This novel approach can be exploited to relax the Persistence of Excitation requirement, enabling an accurate estimation in a wider variety of scenarios. Numerical simulations across various current profiles, including one that guarantees persistent excitation and real-world driving cycles, validate the robustness of the estimator under both noiseless and noisy conditions. Experimental results from lithium-ion and vanadium redox-flow battery setups further corroborate the accuracy of the architecture, demonstrating its capability to estimate Open Circuit Voltage and reconstruct terminal voltage effectively. |
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