Trying to set up the flavanolic phases during grape seed ripening: A spectral and chemical approach

[EN] Grape seeds were collected in ten different dates and classified in seven groups according to their individual hyperspectral imaging characteristics. Proanthocyanidin composition was studied using HPLC-MS for oligomers and acid catalyzed cleavage for polymers characterization. The combination o...

Descripción completa

Detalles Bibliográficos
Autores: Quijada-Morín, Natalia, García Estévez, Ignacio, Nogales-Bueno, Julio, Rodríguez-Pulido, Francisco J., Heredia, Francisco J., Rivas Gonzalo, Julián C., Escribano Bailón, María Teresa, Hernández-Hierro, José Miguel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2016
País:España
Institución:Universidad de Salamanca (USAL)
Repositorio:GREDOS. Repositorio Institucional de la Universidad de Salamanca
OAI Identifier:oai:gredos.usal.es:10366/141144
Acceso en línea:http://hdl.handle.net/10366/141144
Access Level:acceso abierto
Palabra clave:Grape seeds
Hyperspectral image
Proanthocyanidins
HPLC-MS
Phloroglucinolysis
Descripción
Sumario:[EN] Grape seeds were collected in ten different dates and classified in seven groups according to their individual hyperspectral imaging characteristics. Proanthocyanidin composition was studied using HPLC-MS for oligomers and acid catalyzed cleavage for polymers characterization. The combination of both analysis provided a complete description of the flavanols. Chemometric analysis was performed to summarize the analytical results. None of the considered variables presented statistical differences among all groups. From one to five groups were found for each variable, while three was the most frequent value, consequently three putative stages might be considered the real number of different analytical stages since it is the number of statistically significant groups for the majority of the compounds. This classification could be considered as the first step to optimize the use of seeds in winemaking to minimize the gap between sugar and phenolic maturities, consequence of the global climate change, mainly observed in warm climate.