Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides

Bifunctional aminotriphenolate complexes derived from trivalent metals (M = Co, Mn, Cr) have been prepared and structurally characterized. These complexes are octahedral in the solid state but infer dynamic behavior of the ligated dimethylaminopyridine (DMAP) ligands that can function as initiators...

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Detalles Bibliográficos
Autores: Martín, Carmen, Pizzolante, Antonella, Escudero-Adán, Eduardo C., Kleij, Arjan W.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/356186
Acceso en línea:http://hdl.handle.net/2072/356186
https://doi.org/10.1002/ejic.201800142
Access Level:acceso abierto
Palabra clave:54
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spelling Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and EpoxidesMartín, CarmenPizzolante, AntonellaEscudero-Adán, Eduardo C.Kleij, Arjan W.54Bifunctional aminotriphenolate complexes derived from trivalent metals (M = Co, Mn, Cr) have been prepared and structurally characterized. These complexes are octahedral in the solid state but infer dynamic behavior of the ligated dimethylaminopyridine (DMAP) ligands that can function as initiators in the ring-opening copolymerization of cyclic anhydrides and epoxides. More specifically, the ring-opening copolymerization of cyclohexene oxide and phthalic anhydride was studied in detail, and the bifunctional Cr(III) complex gave overall the best results in terms of overall activity and polyester quality.2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersion1921 p.application/pdfhttp://hdl.handle.net/2072/356186https://doi.org/10.1002/ejic.201800142RECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésL'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:2072/3561862026-05-29T05:05:01Z
dc.title.none.fl_str_mv Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides
title Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides
spellingShingle Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides
Martín, Carmen
54
title_short Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides
title_full Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides
title_fullStr Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides
title_full_unstemmed Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides
title_sort Bifunctional Aminotriphenolate Complexes as One-Component Catalysts for the ROCOP of Cyclic Anhydrides and Epoxides
dc.creator.none.fl_str_mv Martín, Carmen
Pizzolante, Antonella
Escudero-Adán, Eduardo C.
Kleij, Arjan W.
author Martín, Carmen
author_facet Martín, Carmen
Pizzolante, Antonella
Escudero-Adán, Eduardo C.
Kleij, Arjan W.
author_role author
author2 Pizzolante, Antonella
Escudero-Adán, Eduardo C.
Kleij, Arjan W.
author2_role author
author
author
dc.subject.none.fl_str_mv 54
topic 54
description Bifunctional aminotriphenolate complexes derived from trivalent metals (M = Co, Mn, Cr) have been prepared and structurally characterized. These complexes are octahedral in the solid state but infer dynamic behavior of the ligated dimethylaminopyridine (DMAP) ligands that can function as initiators in the ring-opening copolymerization of cyclic anhydrides and epoxides. More specifically, the ring-opening copolymerization of cyclohexene oxide and phthalic anhydride was studied in detail, and the bifunctional Cr(III) complex gave overall the best results in terms of overall activity and polyester quality.
publishDate 2018
dc.date.none.fl_str_mv 2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/356186
https://doi.org/10.1002/ejic.201800142
url http://hdl.handle.net/2072/356186
https://doi.org/10.1002/ejic.201800142
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 1921 p.
application/pdf
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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